SAHLINITE Mineral Details

Complete mineralogical data for SAHLINITE. Chemical Formula: Pb14(AsO4)2O9Cl4. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

SAHLINITE

Pb14(AsO4)2O9Cl4

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/c

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenate, vanadate: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with large cations, (OH, etc.):RO4 = 1:1; double sheets // (010) consisting of 2 sheets of Pb(O,Cl)5-8 polyhedra connected by RO4 tetrahedra linked to adjacent double sheets by layer of Cl atoms; structure is related to litharge.1 Isostructural with kombatite, V analog; both are derivatives of litharge form of PbO; in structure there are 7 independent Pb atoms, linked to Cl ± O atoms with [5]- or [8]-coordination; coordination polyhedra are irregularly shaped, due to 6s2 lone-pair effect displayed by Pb2+; structure, projected down (001); constructed by alternation along [010] of 2 distinct structural units: complex unit with composition [Pb14(AsO4)2O9]4+ is n glide (at y = ¼ & ¾); 2nd grp is compound layer of Φ8—Pb8—O15□—Pb6As2—Φ6O2; 2 layers sit back-to-back with As—O tetrahedral apices pointing at each other to make up full module, & are linked by longer Pb—O bonds involing O10 atoms; here are 7 independent Pb atoms in structure, which can be roughly divided in 2 grp; Pb 1 to Pb4 are linked to both O & Cl atoms, [7]- [8]-coordinated; O & Cl atoms lie in 2 planes on opposite side of cation, resp; polyhedra are □ antiprisms or diminished □ antiprisms; Pb5 to Pb7 are linked to O only, [5] – [6]-coordinated; anions define open, irregular-shaped polyhedra.2

Cell Data

a=12.70Å, b=22.58Å, c=11.29Å, ß=118.4o, Z=4

Geology & Identification

Geologic Occurrence

Component of layered Mn-oresSAHLINITESAHLINITE

Habit

Anhedral micro grains

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

As analog of kombatite; structure is similar to litharge

If you are fascinated by the hidden structures of our planet, you have likely come across SAHLINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about SAHLINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, SAHLINITE is defined by the chemical formula Pb14(AsO4)2O9Cl4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. SAHLINITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For SAHLINITE, the dimensions of this microscopic building block are:
a=12.70Å, b=22.58Å, c=11.29Å, ß=118.4o, Z=4
The internal arrangement of these atoms is described as:
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Phosphates, arsenate, vanadate: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with large cations, (OH, etc.):RO4 = 1:1; double sheets // (010) consisting of 2 sheets of Pb(O,Cl)5-8 polyhedra connected by RO4 tetrahedra linked to adjacent double sheets by layer of Cl atoms; structure is related to litharge.1 Isostructural with kombatite, V analog; both are derivatives of litharge form of PbO; in structure there are 7 independent Pb atoms, linked to Cl ± O atoms with [5]- or [8]-coordination; coordination polyhedra are irregularly shaped, due to 6s2 lone-pair effect displayed by Pb2+; structure, projected down (001); constructed by alternation along [010] of 2 distinct structural units: complex unit with composition [Pb14(AsO4)2O9]4+ is n glide (at y = ¼ & ¾); 2nd grp is compound layer of Φ8—Pb8—O15□—Pb6As2—Φ6O2; 2 layers sit back-to-back with As—O tetrahedral apices pointing at each other to make up full module, & are linked by longer Pb—O bonds involing O10 atoms; here are 7 independent Pb atoms in structure, which can be roughly divided in 2 grp; Pb 1 to Pb4 are linked to both O & Cl atoms, [7]- [8]-coordinated; O & Cl atoms lie in 2 planes on opposite side of cation, resp; polyhedra are □ antiprisms or diminished □ antiprisms; Pb5 to Pb7 are linked to O only, [5] – [6]-coordinated; anions define open, irregular-shaped polyhedra.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find SAHLINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Anhedral micro grains
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If SAHLINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Component of layered Mn-oresKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. SAHLINITE is often related to other species, either through similar chemistry or structure.Relationship Data: As analog of kombatite; structure is similar to lithargeUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of SAHLINITE?The standard chemical formula for SAHLINITE is Pb14(AsO4)2O9Cl4. This defines its elemental composition.
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2. Which crystal system does SAHLINITE belong to?SAHLINITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is SAHLINITE typically found in nature?The “habit” or typical appearance of SAHLINITE is described as Anhedral micro grains. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does SAHLINITE form?SAHLINITE is typically found in environments described as: Component of layered Mn-ores. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to SAHLINITE?Yes, it is often associated with or related to other minerals such as: As analog of kombatite; structure is similar to litharge.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of SAHLINITE, we recommend checking high-authority databases:

Final Thoughts

SAHLINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb14(AsO4)2O9Cl4 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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