SCHÜLLERITE Mineral Details

Complete mineralogical data for SCHÜLLERITE. Chemical Formula: Ba2Na2Mg2Ti2[Si2O7]2O2F2. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

SCHÜLLERITE

Ba2Na2Mg2Ti2[Si2O7]2O2F2

Crystal System

Triclinic

Crystal Class

Pedial

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Has heterophyllosilicate structure with isolated HOH-type layers where octahedral O sheet has 4 octahedral positions occupied by Na,Mn,Fe3+,Fe2+ while heteropolyhedral H—sheets are composed of 2 diff diortho grp Si2O7 linked by 2 diff Ti □∆; Ba[11] is loc btw HOH layers in 2 structural positions, related to lamprophyllite grp, but diff from them by topology of HOH layers.3 Alternation of TS & I blocks; TS block composed of central O sheet, there are 2 brookite-like chains of Mo octahedra, [Mg2 O8]12-[Mo(1)] & [Na2O8]14-[Mo(2)], ideal composition of O sheet is (Na2Mg2O2 F2]0; H sheet is composed of[5]-coordinated Ti-dominant MH polyhedra & Si2O7 grp; composition of 2 H sheets is [Ti2(Si2O7)2]4-; TS block has topology characteristic of Grp IV of TS-block minerals: 2 H sheets connect to O sheet such that 2 Si2O7 grp link to Mg-dominant octahedra of O sheet adjacent along t1; in O sheet, occurrence of divalent cations at Mo(1) site results in presence of monovalent anions, F-, at XoA site; Ap site of H sheet is occupied mainly by Ba: Ap site is shifted from plane of H sheet, & Ba atoms constitute I block of composition [Ba2]4+; schullerite is only mineral of Grp IV that has (1) brookite-like [Mg2O8]12- chain of octahedra in O sheet, (2) [5]-coordinated Ti in H sheet, (3) Ba atoms in I block.4 Structures of lamprophyllite-related minerals are based on HOH modules of central octahedral O sheet sandwiched btw 2 heteropolyhedral H sheets; xl GF for these minerals as [10-22]A2[6]M1[6]M22[6]M3X2 [5]L2(Si2 O7)2O2], where contents of O & H sheets are given in [] brackets in this order & A = Ba,Sr,K,Na; M1 = Na, Mn2+; M2 = Na,Mn2+,Fe2+,Ca; M3 = Ti,Mn2+,Mg,Fe3+,Fe2+; L = Ti,Fe3+; X = OH,O,F; according to unit-cell parameters & symmetry, lamprophyllite-related minerals structure types: I (monocinic polytypes, C2/m); II (orthorhombic polytypes, Pnmn), III (nabalamprophyllite, BaNa[Na3Ti(OH)2][Ti2(Si2O7)2O2], monoclinic, P2/m, with ordered array of interlayer Ba2+ & Na+ cations), IV (triclinic, P1) & V (triclinic, P1); triclinic members (IV & V) incl schüllerite & its analogs, which diff from lamprophyllite-grp minerals sensu stricto in their symmetry & topology & HOH modules; end-member formulae of lamprophyllite-related minerals & position of schüllerite in ranks of heterophyllosilicates.6

Cell Data

a=5.396Å, b=7.071Å, c=10.226Å, α=99.736o, ß=99.55o, γ=90.09o, Z=1

Geology & Identification

Geologic Occurrence

In miarolic cavities in alkaline basaltSCHÜLLERITESCHÜLLERITE

Habit

Flattened brown crystals

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Lamprophyllite group; compare rosenbuschite group

If you are fascinated by the hidden structures of our planet, you have likely come across SCHÜLLERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about SCHÜLLERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, SCHÜLLERITE is defined by the chemical formula Ba2Na2Mg2Ti2[Si2O7]2O2F2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. SCHÜLLERITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pedial.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For SCHÜLLERITE, the dimensions of this microscopic building block are:
a=5.396Å, b=7.071Å, c=10.226Å, α=99.736o, ß=99.55o, γ=90.09o, Z=1
The internal arrangement of these atoms is described as:
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Has heterophyllosilicate structure with isolated HOH-type layers where octahedral O sheet has 4 octahedral positions occupied by Na,Mn,Fe3+,Fe2+ while heteropolyhedral H—sheets are composed of 2 diff diortho grp Si2O7 linked by 2 diff Ti □∆; Ba[11] is loc btw HOH layers in 2 structural positions, related to lamprophyllite grp, but diff from them by topology of HOH layers.3 Alternation of TS & I blocks; TS block composed of central O sheet, there are 2 brookite-like chains of Mo octahedra, [Mg2 O8]12-[Mo(1)] & [Na2O8]14-[Mo(2)], ideal composition of O sheet is (Na2Mg2O2 F2]0; H sheet is composed of[5]-coordinated Ti-dominant MH polyhedra & Si2O7 grp; composition of 2 H sheets is [Ti2(Si2O7)2]4-; TS block has topology characteristic of Grp IV of TS-block minerals: 2 H sheets connect to O sheet such that 2 Si2O7 grp link to Mg-dominant octahedra of O sheet adjacent along t1; in O sheet, occurrence of divalent cations at Mo(1) site results in presence of monovalent anions, F-, at XoA site; Ap site of H sheet is occupied mainly by Ba: Ap site is shifted from plane of H sheet, & Ba atoms constitute I block of composition [Ba2]4+; schullerite is only mineral of Grp IV that has (1) brookite-like [Mg2O8]12- chain of octahedra in O sheet, (2) [5]-coordinated Ti in H sheet, (3) Ba atoms in I block.4 Structures of lamprophyllite-related minerals are based on HOH modules of central octahedral O sheet sandwiched btw 2 heteropolyhedral H sheets; xl GF for these minerals as [10-22]A2[6]M1[6]M22[6]M3X2 [5]L2(Si2 O7)2O2], where contents of O & H sheets are given in [] brackets in this order & A = Ba,Sr,K,Na; M1 = Na, Mn2+; M2 = Na,Mn2+,Fe2+,Ca; M3 = Ti,Mn2+,Mg,Fe3+,Fe2+; L = Ti,Fe3+; X = OH,O,F; according to unit-cell parameters & symmetry, lamprophyllite-related minerals structure types: I (monocinic polytypes, C2/m); II (orthorhombic polytypes, Pnmn), III (nabalamprophyllite, BaNa[Na3Ti(OH)2][Ti2(Si2O7)2O2], monoclinic, P2/m, with ordered array of interlayer Ba2+ & Na+ cations), IV (triclinic, P1) & V (triclinic, P1); triclinic members (IV & V) incl schüllerite & its analogs, which diff from lamprophyllite-grp minerals sensu stricto in their symmetry & topology & HOH modules; end-member formulae of lamprophyllite-related minerals & position of schüllerite in ranks of heterophyllosilicates.6This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find SCHÜLLERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Flattened brown crystals
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If SCHÜLLERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In miarolic cavities in alkaline basaltKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. SCHÜLLERITE is often related to other species, either through similar chemistry or structure.Relationship Data: Lamprophyllite group; compare rosenbuschite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of SCHÜLLERITE?The standard chemical formula for SCHÜLLERITE is Ba2Na2Mg2Ti2[Si2O7]2O2F2. This defines its elemental composition.2. Which crystal system does SCHÜLLERITE belong to?SCHÜLLERITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pedial class.3. How is SCHÜLLERITE typically found in nature?The “habit” or typical appearance of SCHÜLLERITE is described as Flattened brown crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does SCHÜLLERITE form?SCHÜLLERITE is typically found in environments described as: In miarolic cavities in alkaline basalt. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to SCHÜLLERITE?Yes, it is often associated with or related to other minerals such as: Lamprophyllite group; compare rosenbuschite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of SCHÜLLERITE, we recommend checking high-authority databases:

Final Thoughts

SCHÜLLERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ba2Na2Mg2Ti2[Si2O7]2O2F2 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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