SELIGMANNITE Mineral Details

Complete mineralogical data for SELIGMANNITE. Chemical Formula: PbCuAsS3. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

SELIGMANNITE

PbCuAsS3

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Pn21m

Point Group

m m 2

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; Pb[7,8] polyhedra, (As,Sb)S3 ∆ & CuS4 tetrahedra share corners & edges to form 3-D framework; Cu4 tetrahedra share corners to form chains // [001].2 2 sulfosalt structures are isotypic; Pb(1) atoms are surrounded by 8 S atoms, Pb(2) atoms by 7 S atoms; Sb resp As atoms have trig ∆ coordination by S atoms; SbS3 resp AsS3 ∆ are isolated; Sb— S resp As— S distances are in good agreement with Sb— S resp As— S covalent-bond length; Cu atoms are slightly deformed tetrahedrally coordinated by 4 S atoms; Cu tetrahedra are sharing corners || to c axis.3

Cell Data

a=8.08Å, b=8.74Å, c=7.63Å, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermal veins formed at moderate temperaturesSELIGMANNITESELIGMANNITE

Habit

Short prismatic to tabular, striated macro crystals; massive, granular, compact

Twinning

On {110} commonly forming cross or cogwheel aggregates

Relationships

RELATIONSHIP TO OTHER MINERALS

Bournonite group; forms series with bournonite

If you are fascinated by the hidden structures of our planet, you have likely come across SELIGMANNITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about SELIGMANNITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, SELIGMANNITE is defined by the chemical formula PbCuAsS3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. SELIGMANNITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Pn21m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For SELIGMANNITE, the dimensions of this microscopic building block are:
a=8.08Å, b=8.74Å, c=7.63Å, Z=4
The internal arrangement of these atoms is described as:Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; Pb[7,8] polyhedra, (As,Sb)S3 ∆ & CuS4 tetrahedra share corners & edges to form 3-D framework; Cu4 tetrahedra share corners to form chains // [001].2 2 sulfosalt structures are isotypic; Pb(1) atoms are surrounded by 8 S atoms, Pb(2) atoms by 7 S atoms; Sb resp As atoms have trig ∆ coordination by S atoms; SbS3 resp AsS3 ∆ are isolated; Sb— S resp As— S distances are in good agreement with Sb— S resp As— S covalent-bond length; Cu atoms are slightly deformed tetrahedrally coordinated by 4 S atoms; Cu tetrahedra are sharing corners || to c axis.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find SELIGMANNITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short prismatic to tabular, striated macro crystals; massive, granular, compact
  • Twinning: On {110} commonly forming cross or cogwheel aggregates
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If SELIGMANNITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermal veins formed at moderate temperaturesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. SELIGMANNITE is often related to other species, either through similar chemistry or structure.Relationship Data: Bournonite group; forms series with bournoniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of SELIGMANNITE?The standard chemical formula for SELIGMANNITE is PbCuAsS3. This defines its elemental composition.2. Which crystal system does SELIGMANNITE belong to?SELIGMANNITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.
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3. How is SELIGMANNITE typically found in nature?The “habit” or typical appearance of SELIGMANNITE is described as Short prismatic to tabular, striated macro crystals; massive, granular, compact. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does SELIGMANNITE form?SELIGMANNITE is typically found in environments described as: In hydrothermal veins formed at moderate temperatures. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to SELIGMANNITE?Yes, it is often associated with or related to other minerals such as: Bournonite group; forms series with bournonite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of SELIGMANNITE, we recommend checking high-authority databases:

Final Thoughts

SELIGMANNITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbCuAsS3 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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