SERPIERITE Mineral Details

Complete mineralogical data for SERPIERITE. Chemical Formula: Ca(Cu,Zn)4(SO4)2(OH)6(H2O)3. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

SERPIERITE

Ca(Cu,Zn)4(SO4)2(OH)6(H2O)3

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/c

Point Group

2/m

Structure & Data

Crystal Structure

Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, sheets of edge-sharing octahedra; similar sheets as ktenasite // (100) linked by sharing corners with [CaO4(H2O)2 (H2O)] pseudo-octahedra; sheets in these structure linked by H—bonding.2 In xl structure there are Ca ions in [7]-coordination, Cu ions in both distorted octahedra & [4+2]-coordination & slightly distorted SO4 tetrahedra; all bond distances are within limits given in literature; presence of new complex sheet of Cu coordination polyhedra, || to (100).3 [Cu4(SO4)(OH)6(H2O)]o sheet in wroewolfeite is also found in posnjakite & may also occur in langite; this & other related sheets may be described by GF [M4XnΦ8-n], in which M = octahedrally coordinated cation, X = complex anion, Φ = simple anion (e.g. O2-, (OH)-, (H2O)o); t following structures are incl: n = 0, botallackite; n = 1, wroewolfeite, langite, posnjakite; n = 2, ktenasite, serpierite, devillite; intramodule linkages & hydration states in these minerals may be interpreted in terms of Lewis basicity/acidity of structural fragments.4

Cell Data

a=22.19Å, b=6.25Å, c=21.85Å, ß=113.4o, Z=8

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of metallic sulfide skarn depositSERPIERITESERPIERITE

Habit

In tufts of micro crystals, elongated, bladed

Twinning

Polysynthetic as twin plane, ubiquitous

Relationships

RELATIONSHIP TO OTHER MINERALS

Devilline group; dimorphous with orthoserpierite

If you are fascinated by the hidden structures of our planet, you have likely come across SERPIERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about SERPIERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, SERPIERITE is defined by the chemical formula Ca(Cu,Zn)4(SO4)2(OH)6(H2O)3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. SERPIERITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For SERPIERITE, the dimensions of this microscopic building block are:
a=22.19Å, b=6.25Å, c=21.85Å, ß=113.4o, Z=8
The internal arrangement of these atoms is described as:Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, sheets of edge-sharing octahedra; similar sheets as ktenasite // (100) linked by sharing corners with [CaO4(H2O)2 (H2O)] pseudo-octahedra; sheets in these structure linked by H—bonding.2 In xl structure there are Ca ions in [7]-coordination, Cu ions in both distorted octahedra & [4+2]-coordination & slightly distorted SO4 tetrahedra; all bond distances are within limits given in literature; presence of new complex sheet of Cu coordination polyhedra, || to (100).3 [Cu4(SO4)(OH)6(H2O)]o sheet in wroewolfeite is also found in posnjakite & may also occur in langite; this & other related sheets may be described by GF [M4XnΦ8-n], in which M = octahedrally coordinated cation, X = complex anion, Φ = simple anion (e.g. O2-, (OH)-, (H2O)o); t following structures are incl: n = 0, botallackite; n = 1, wroewolfeite, langite, posnjakite; n = 2, ktenasite, serpierite, devillite; intramodule linkages & hydration states in these minerals may be interpreted in terms of Lewis basicity/acidity of structural fragments.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find SERPIERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: In tufts of micro crystals, elongated, bladed
  • Twinning: Polysynthetic as twin plane, ubiquitous
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If SERPIERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of metallic sulfide skarn depositKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. SERPIERITE is often related to other species, either through similar chemistry or structure.Relationship Data: Devilline group; dimorphous with orthoserpieriteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of SERPIERITE?The standard chemical formula for SERPIERITE is Ca(Cu,Zn)4(SO4)2(OH)6(H2O)3. This defines its elemental composition.
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2. Which crystal system does SERPIERITE belong to?SERPIERITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is SERPIERITE typically found in nature?The “habit” or typical appearance of SERPIERITE is described as In tufts of micro crystals, elongated, bladed. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does SERPIERITE form?SERPIERITE is typically found in environments described as: Secondary mineral in oxidized zone of metallic sulfide skarn deposit. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to SERPIERITE?Yes, it is often associated with or related to other minerals such as: Devilline group; dimorphous with orthoserpierite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of SERPIERITE, we recommend checking high-authority databases:

Final Thoughts

SERPIERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca(Cu,Zn)4(SO4)2(OH)6(H2O)3 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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