SHIGAITE Mineral Details

Complete mineralogical data for SHIGAITE. Chemical Formula: NaMn6Al3(OH)18(SO4)2(H2O)6·6H2O. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

SHIGAITE

NaMn6Al3(OH)18(SO4)2(H2O)6·6H2O

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal rhombohedral

Space Group

R3

Point Group

3

Structure & Data

Crystal Structure

Sulfates, selenates, tellurates are typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, sheets of edge-sharing octahedra; brucite-like sheets of edge-sharing M(OH)6 octahedra alternating with interlayer sheet composed of H2O molecules & sufficient SO4 to balance + charge in brucite-like layer; analog to hydrotalcite structure; cations can be lodged in interlayer sheet.2 Structural unit of shigaite is planar sheet of edge-sharing octahedra, [AlMn2+2(OH)6]1+; these oxycation sheets are intercalated with oxyanion sheets of chemical composition Na(H2O)6{H2O}6 (SO4)2; H—bonding plays major role in linkage both within oxyanion sheet & btw structural unit & oxyanion sheet of interstitial species.3

Cell Data

a=9.51Å, c=33.07Å, Z=3

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zones of Cu-depositsSHIGAITESHIGAITE

Habit

Fibrous, spherulitic

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Hydrotalcite supergroup, wermlandite group

If you are fascinated by the hidden structures of our planet, you have likely come across SHIGAITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about SHIGAITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, SHIGAITE is defined by the chemical formula NaMn6Al3(OH)18(SO4)2(H2O)6·6H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. SHIGAITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal rhombohedral.
  • Point Group: 3
  • Space Group: R3
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For SHIGAITE, the dimensions of this microscopic building block are:
a=9.51Å, c=33.07Å, Z=3
The internal arrangement of these atoms is described as:Sulfates, selenates, tellurates are typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, sheets of edge-sharing octahedra; brucite-like sheets of edge-sharing M(OH)6 octahedra alternating with interlayer sheet composed of H2O molecules & sufficient SO4 to balance + charge in brucite-like layer; analog to hydrotalcite structure; cations can be lodged in interlayer sheet.2 Structural unit of shigaite is planar sheet of edge-sharing octahedra, [AlMn2+2(OH)6]1+; these oxycation sheets are intercalated with oxyanion sheets of chemical composition Na(H2O)6{H2O}6 (SO4)2; H—bonding plays major role in linkage both within oxyanion sheet & btw structural unit & oxyanion sheet of interstitial species.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find SHIGAITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Fibrous, spherulitic
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If SHIGAITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zones of Cu-depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. SHIGAITE is often related to other species, either through similar chemistry or structure.Relationship Data: Hydrotalcite supergroup, wermlandite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of SHIGAITE?The standard chemical formula for SHIGAITE is NaMn6Al3(OH)18(SO4)2(H2O)6·6H2O. This defines its elemental composition.2. Which crystal system does SHIGAITE belong to?SHIGAITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal rhombohedral class.
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3. How is SHIGAITE typically found in nature?The “habit” or typical appearance of SHIGAITE is described as Fibrous, spherulitic. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does SHIGAITE form?SHIGAITE is typically found in environments described as: Secondary mineral in oxidized zones of Cu-deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to SHIGAITE?Yes, it is often associated with or related to other minerals such as: Hydrotalcite supergroup, wermlandite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of SHIGAITE, we recommend checking high-authority databases:

Final Thoughts

SHIGAITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of NaMn6Al3(OH)18(SO4)2(H2O)6·6H2O and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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