STEPHANITE Mineral Details

Complete mineralogical data for STEPHANITE. Chemical Formula: Ag5SbS4. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

STEPHANITE

Ag5SbS4

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Cmc21

Point Group

m m 2

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; attributed to lone-electron-pair effect of metalloid ions; XS3 ∆, neso-sulfarsenites, etc., Ag[3] triangles connect SbS3 ∆ which point same direction, resulting in polar structure; Ag—Ag metallic bonding in (023) plane.1 Complex, subcoordination, pseudohexagonal structure, in which tigonal SbS3 ∆ are isolated & bound via AgS3 triangles & AgS4 tetrahedra; Ag-tetrahedra are tied together at apices & along edges.2 Sb atoms have trig-∆ coordination by S atoms; Sb—S distances of 2.47 (2x) & 2.48 Å are in good agreement with Sb—S covalent bond length; SbS3 ∆ are isolated; Ag(1) has planar [3] coordination with Ag—S 2.51 & 2.55 Å (2x); Ag(2) & Ag(3) have 3 nearest neighbors btw 2.49 & 2.72 Å with which they form grp which is very flat ∆; 4th S atom around Ag(2) & Ag(3) is at mid distance of 3.00 & 2.92 Å in addition each Ag(2) has 1 Ag(3) at 2.95, 1 Ag(2) at 2.96 & 1 Ag(3) at 2.97 Å; Ag(3) too has in addition 1 Ag(3) at 2.91, 1 Ag(2) at 2.95 & 1 Ag(2) at 2.97 Å; these Ag—Ag distances correspond to metal—metal bonds; metal atoms form layer || to (023) plane; S atoms hold metal atoms in & btw layers together.3 In structure of stephanite, Sb forms isolated SbS3 ∆, which typically occur in sulfosalts, & Ag occupies sites with coordination ranging from triangular to almost tetrahedral; both Sb—S & Ag—S bond distances closely match values commonly observed in structures of other Ag sulfosalts & sulfides; use of non-harmonic parameters for Ag allowed better description of electron density related to Ag, which is usually difficult to refine in good ionic conductors; careful analysis of energy barriers btw Ag sites defines preferred ion diffusion pathways within xl structure of stephanite; diffusion of Ag ions occurs preferentially along sites Ag1 & Ag2, giving rise to 2-D-nets of Ag atoms in which ion conduction probably takes place.4

Cell Data

a=7.84Å, b=12.47Å, c=8.54Å, Z=4

Geology & Identification

Geologic Occurrence

A late-stage mineral in hydrothermal silver depositsSTEPHANITESTEPHANITE

Habit

Short prismatic to tabular macro crystals, striated; massive, compact, disseminated

Twinning

On {110}, {130}, {100} and {010}, with plane {001}

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare selenostephanite

If you are fascinated by the hidden structures of our planet, you have likely come across STEPHANITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about STEPHANITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, STEPHANITE is defined by the chemical formula Ag5SbS4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. STEPHANITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Cmc21
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For STEPHANITE, the dimensions of this microscopic building block are:
a=7.84Å, b=12.47Å, c=8.54Å, Z=4
The internal arrangement of these atoms is described as:
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Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; attributed to lone-electron-pair effect of metalloid ions; XS3 ∆, neso-sulfarsenites, etc., Ag[3] triangles connect SbS3 ∆ which point same direction, resulting in polar structure; Ag—Ag metallic bonding in (023) plane.1 Complex, subcoordination, pseudohexagonal structure, in which tigonal SbS3 ∆ are isolated & bound via AgS3 triangles & AgS4 tetrahedra; Ag-tetrahedra are tied together at apices & along edges.2 Sb atoms have trig-∆ coordination by S atoms; Sb—S distances of 2.47 (2x) & 2.48 Å are in good agreement with Sb—S covalent bond length; SbS3 ∆ are isolated; Ag(1) has planar [3] coordination with Ag—S 2.51 & 2.55 Å (2x); Ag(2) & Ag(3) have 3 nearest neighbors btw 2.49 & 2.72 Å with which they form grp which is very flat ∆; 4th S atom around Ag(2) & Ag(3) is at mid distance of 3.00 & 2.92 Å in addition each Ag(2) has 1 Ag(3) at 2.95, 1 Ag(2) at 2.96 & 1 Ag(3) at 2.97 Å; Ag(3) too has in addition 1 Ag(3) at 2.91, 1 Ag(2) at 2.95 & 1 Ag(2) at 2.97 Å; these Ag—Ag distances correspond to metal—metal bonds; metal atoms form layer || to (023) plane; S atoms hold metal atoms in & btw layers together.3 In structure of stephanite, Sb forms isolated SbS3 ∆, which typically occur in sulfosalts, & Ag occupies sites with coordination ranging from triangular to almost tetrahedral; both Sb—S & Ag—S bond distances closely match values commonly observed in structures of other Ag sulfosalts & sulfides; use of non-harmonic parameters for Ag allowed better description of electron density related to Ag, which is usually difficult to refine in good ionic conductors; careful analysis of energy barriers btw Ag sites defines preferred ion diffusion pathways within xl structure of stephanite; diffusion of Ag ions occurs preferentially along sites Ag1 & Ag2, giving rise to 2-D-nets of Ag atoms in which ion conduction probably takes place.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find STEPHANITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short prismatic to tabular macro crystals, striated; massive, compact, disseminated
  • Twinning: On {110}, {130}, {100} and {010}, with plane {001}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If STEPHANITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: A late-stage mineral in hydrothermal silver depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. STEPHANITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare selenostephaniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of STEPHANITE?The standard chemical formula for STEPHANITE is Ag5SbS4. This defines its elemental composition.2. Which crystal system does STEPHANITE belong to?STEPHANITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is STEPHANITE typically found in nature?The “habit” or typical appearance of STEPHANITE is described as Short prismatic to tabular macro crystals, striated; massive, compact, disseminated. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does STEPHANITE form?STEPHANITE is typically found in environments described as: A late-stage mineral in hydrothermal silver deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to STEPHANITE?Yes, it is often associated with or related to other minerals such as: Compare selenostephanite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of STEPHANITE, we recommend checking high-authority databases:

Final Thoughts

STEPHANITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ag5SbS4 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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