STILBITE-Na Mineral Details

Complete mineralogical data for STILBITE-Na. Chemical Formula: Na9[Si27Al9O72]·28H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

STILBITE-Na

Na9[Si27Al9O72]·28H2O

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/m

Point Group

2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with sheets with 4-4-1-1 // (010) connected into framework with channels of 10-membered rings // [100] & channels of 8-membered rings // [001].2 Dominated by 6-membered rings of (Al,Si)O4 tetrahedra with channels along [100] & [001].3 Framework type (STI) of stilbite grp, which incl stilbite series, stellerite & barrerite, consists of 2 sets of connected channels; 1 channel extends || to a-axis & is confined by 10-membered ring; other channel is loc along [101] for monoclinic frameworks or [001] for orthorhombic structure & is confined by 8-membered ring; both of these channels are in (010) plane, creating structural weakness across plane leading to prf (010) cleavage & tabular habit; 2 diff orientations have long been used to describe xllo-graphy of stilbite, proper monoclinic setting with ß angle near 127o & pseudo-orthorhombic setting with ß near 91o; 2nd is used for ease of comparison with xl forms & xl structures of stellerite & barrierite.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations or both; molecules of H2O occupy extra-framework positions; stilbite series increasing departure from topological symmetry of orthorhombic framework, Fmmm, tends to correlate with increasing content of monovalent cations, which causes framework to rotate; however, {001} growth sectors with appreciable Na & ortho-rhombic Fmmm symmetry have been observed in xl in which other isochemical sectors are monoclinic, C2/m; centrosymmetric s.g. depends on statistically complete, Si,Al disorder, & true s.g. may be noncentrosymmeric; stilbite-Ca has Ca as most abundant extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7a,7b,8a,8b

Cell Data

a=13.61Å, b=18.33Å, c=11.25Å, ß=127.7o, Z=1

Geology & Identification

Geologic Occurrence

In calcite-quartz veinsSTILBITE-NaSTILBITE-Na

Habit

Euhedral, thick tabular, trapezoedral crystals; aggregates, pinacoid dominated

Twinning

With {100} as twin and contact plane (original)

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family, stilbite subgroup

If you are fascinated by the hidden structures of our planet, you have likely come across STILBITE-Na. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about STILBITE-Na. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, STILBITE-Na is defined by the chemical formula Na9[Si27Al9O72]·28H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. STILBITE-Na crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For STILBITE-Na, the dimensions of this microscopic building block are:
a=13.61Å, b=18.33Å, c=11.25Å, ß=127.7o, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with sheets with 4-4-1-1 // (010) connected into framework with channels of 10-membered rings // [100] & channels of 8-membered rings // [001].2 Dominated by 6-membered rings of (Al,Si)O4 tetrahedra with channels along [100] & [001].3 Framework type (STI) of stilbite grp, which incl stilbite series, stellerite & barrerite, consists of 2 sets of connected channels; 1 channel extends || to a-axis & is confined by 10-membered ring; other channel is loc along [101] for monoclinic frameworks or [001] for orthorhombic structure & is confined by 8-membered ring; both of these channels are in (010) plane, creating structural weakness across plane leading to prf (010) cleavage & tabular habit; 2 diff orientations have long been used to describe xllo-graphy of stilbite, proper monoclinic setting with ß angle near 127o & pseudo-orthorhombic setting with ß near 91o; 2nd is used for ease of comparison with xl forms & xl structures of stellerite & barrierite.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations or both; molecules of H2O occupy extra-framework positions; stilbite series increasing departure from topological symmetry of orthorhombic framework, Fmmm, tends to correlate with increasing content of monovalent cations, which causes framework to rotate; however, {001} growth sectors with appreciable Na & ortho-rhombic Fmmm symmetry have been observed in xl in which other isochemical sectors are monoclinic, C2/m; centrosymmetric s.g. depends on statistically complete, Si,Al disorder, & true s.g. may be noncentrosymmeric; stilbite-Ca has Ca as most abundant extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7a,7b,8a,8bThis internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find STILBITE-Na in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Euhedral, thick tabular, trapezoedral crystals; aggregates, pinacoid dominated
  • Twinning: With {100} as twin and contact plane (original)
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If STILBITE-Na exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In calcite-quartz veinsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. STILBITE-Na is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family, stilbite subgroupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of STILBITE-Na?The standard chemical formula for STILBITE-Na is Na9[Si27Al9O72]·28H2O. This defines its elemental composition.2. Which crystal system does STILBITE-Na belong to?STILBITE-Na crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is STILBITE-Na typically found in nature?The “habit” or typical appearance of STILBITE-Na is described as Euhedral, thick tabular, trapezoedral crystals; aggregates, pinacoid dominated. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does STILBITE-Na form?STILBITE-Na is typically found in environments described as: In calcite-quartz veins. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to STILBITE-Na?Yes, it is often associated with or related to other minerals such as: Zeolite family, stilbite subgroup.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of STILBITE-Na, we recommend checking high-authority databases:

Final Thoughts

STILBITE-Na is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na9[Si27Al9O72]·28H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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