THORITE Mineral Details

Complete mineralogical data for THORITE. Chemical Formula: Th[SiO4]. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

THORITE

Th[SiO4]

Crystal System

Tetragonal

Crystal Class

Ditetragonal dipyramidal

Space Group

I41/amd

Point Group

4/m 2/m 2/m

Structure & Data

Crystal Structure

Nesosilicates: insular SiO4 tetrahedra w/o add’l anions, cations in octahedral [6] &/or greater coordination; zigzag chains of edge-sharing ThO8 triangular dodecahedra // [100] linked into framework by sharing corners & edges with SiO4 tetrahedra; chains of alternating corner-sharing ThO8 octahedra & SiO4 tetrahedra // [001]; isotypes of behierite & xenotime.2 Nb-Ti rich thorite: isostructural with other zircon-grp minerals & has unit cell which is 4% smaller than that of thorite sensu stricto, result of incorporation of high field-strength elements of small radii; structure consists of 1 [8]-coordinated metal site (A = Th,Zr,U,REE,Y,Nb,Ti, etc.), 1 tetrahedral site (T), 1 O site & 1 variably-occupied H site; A site is coordinated by 4 axial O atoms & 4 equatorial O atoms; T site in MSH thorite is only partially occupied by Si (33% vacant) & coordinated by 4 O; partially occupied H site (31%) is loc 0.980 Å away from O atom, forming (O4H4)4- grp when T site is vacant; removal of center of symmetry in structure allows for possibilty of presence of bimodal T-O & A-O bond lengths, leading to both short Si—O bonds & longer □—OH bonds, as well as shorter A—O bonds required for Nb and Ti; lodged of Nb & Ti into thorite structure may be facilitated by increased distortion of AO8 bi-disphenoid, relaxation & shortening of A—O bonds as result of (SiO4)4–(OH)44- substitution & likely presence of defects (O vacancies) in regions which have undergone sight metamictization, resulting in short-range ordering of Nb, Ti & Th; it is possible that metastable, limited solid solution exists btw thorite & (OH)44–dominant thorogummite with intermediate compositions defined by Th(SiO4)1-x (OH)4x, reported compositions indicate otherwise & it is suggested name “thorogummite” be abondoned.4 See “Additiona Structures” tab for entry(s).5

Cell Data

a=7.13Å, c=6.32Å, Z=4

Geology & Identification

Geologic Occurrence

In igneous and metamorphic rocks; in sedimentary rocks, alluvial heavy-mineral sandsTHORITETHORITE

Habit

As tabular to prismatic macro crystals; irregular grains, massive

Twinning

on {101}, geniculated

Relationships

RELATIONSHIP TO OTHER MINERALS

Zircon group; dimorphous with huttonite

If you are fascinated by the hidden structures of our planet, you have likely come across THORITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about THORITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, THORITE is defined by the chemical formula Th[SiO4].This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. THORITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Ditetragonal dipyramidal.
  • Point Group: 4/m 2/m 2/m
  • Space Group: I41/amd
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For THORITE, the dimensions of this microscopic building block are:
a=7.13Å, c=6.32Å, Z=4
The internal arrangement of these atoms is described as:
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Nesosilicates: insular SiO4 tetrahedra w/o add’l anions, cations in octahedral [6] &/or greater coordination; zigzag chains of edge-sharing ThO8 triangular dodecahedra // [100] linked into framework by sharing corners & edges with SiO4 tetrahedra; chains of alternating corner-sharing ThO8 octahedra & SiO4 tetrahedra // [001]; isotypes of behierite & xenotime.2 Nb-Ti rich thorite: isostructural with other zircon-grp minerals & has unit cell which is 4% smaller than that of thorite sensu stricto, result of incorporation of high field-strength elements of small radii; structure consists of 1 [8]-coordinated metal site (A = Th,Zr,U,REE,Y,Nb,Ti, etc.), 1 tetrahedral site (T), 1 O site & 1 variably-occupied H site; A site is coordinated by 4 axial O atoms & 4 equatorial O atoms; T site in MSH thorite is only partially occupied by Si (33% vacant) & coordinated by 4 O; partially occupied H site (31%) is loc 0.980 Å away from O atom, forming (O4H4)4- grp when T site is vacant; removal of center of symmetry in structure allows for possibilty of presence of bimodal T-O & A-O bond lengths, leading to both short Si—O bonds & longer □—OH bonds, as well as shorter A—O bonds required for Nb and Ti; lodged of Nb & Ti into thorite structure may be facilitated by increased distortion of AO8 bi-disphenoid, relaxation & shortening of A—O bonds as result of (SiO4)4–(OH)44- substitution & likely presence of defects (O vacancies) in regions which have undergone sight metamictization, resulting in short-range ordering of Nb, Ti & Th; it is possible that metastable, limited solid solution exists btw thorite & (OH)44–dominant thorogummite with intermediate compositions defined by Th(SiO4)1-x (OH)4x, reported compositions indicate otherwise & it is suggested name “thorogummite” be abondoned.4 See “Additiona Structures” tab for entry(s).5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find THORITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As tabular to prismatic macro crystals; irregular grains, massive
  • Twinning: on {101}, geniculated
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If THORITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In igneous and metamorphic rocks; in sedimentary rocks, alluvial heavy-mineral sandsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. THORITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zircon group; dimorphous with huttoniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of THORITE?The standard chemical formula for THORITE is Th[SiO4]. This defines its elemental composition.2. Which crystal system does THORITE belong to?THORITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Ditetragonal dipyramidal class.3. How is THORITE typically found in nature?The “habit” or typical appearance of THORITE is described as As tabular to prismatic macro crystals; irregular grains, massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does THORITE form?THORITE is typically found in environments described as: In igneous and metamorphic rocks; in sedimentary rocks, alluvial heavy-mineral sands. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to THORITE?Yes, it is often associated with or related to other minerals such as: Zircon group; dimorphous with huttonite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of THORITE, we recommend checking high-authority databases:

Final Thoughts

THORITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Th[SiO4] and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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