TILLEYITE Mineral Details

Complete mineralogical data for TILLEYITE. Chemical Formula: Ca5[Si2O7](CO3)2. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

TILLEYITE

Ca5[Si2O7](CO3)2

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/a

Point Group

2/m

Structure & Data

Crystal Structure

Sorosilicates: of SiO4 tetrahedras combined mainly in pairs, also in larger combos which form isolated grp; Si2O7 grp with add’l anions, cations in octahedral [6] &/or other coordination; edge-sharing deformed CaO6 octahedra form 2-periodic single chains & double chains // [001]; corner-sharing of octahedra in double chains, & linked by Si2O7 grp creates ribbons // (100) linked by single chains & CO3 grp.1 Consisting of columns of Ca octahedra along c axis, which are linked into walls; in corrugated strip along b axis; these walls are linked by Si2O7 grp oriented along c axis; corrugated strips are held by separate Ca octahedra & CO3 grp; Ca octahedra & Si tetrahedra are very distorted.2 Distortions of columns of Ca—O octahedra are mostly explainable by shortening of shared edges; in Si2O7 grp Si—O bridge bonds are 1.656(7) & 1.678(7) Å & peripheral bonds are 1.602(7) & 1.616(7) Å & peripheral bonds are 1.602(7) & 1.617(7) Å & bridging Si—O—Si angle is 157o; inner O—O edges (avg 2.58 Å) are shorter than outer edges (2.71 Å), consistent with Coulombic forces in Si2O7 grp & with л-bonding mechanism.3 Consist of (CO3) grp in 1 layer, whereas (CaO8) polyhedra intertwine [Si2O7] pairs of tetrahedra in outer layer.4

Cell Data

a=15.11Å, b=10.24Å, c=7.58Å, ß=105.2o, Z=4

Geology & Identification

Geologic Occurrence

In contact metamorphic zone between igneous rocks and limestones, formed at low pressure and high temperatureTILLEYITETILLEYITE

Habit

As subhedral crystals, rounded grains, irregular plates

Twinning

On {100}, simple; rarely, lamellar

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across TILLEYITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about TILLEYITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, TILLEYITE is defined by the chemical formula Ca5[Si2O7](CO3)2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. TILLEYITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/a
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For TILLEYITE, the dimensions of this microscopic building block are:
a=15.11Å, b=10.24Å, c=7.58Å, ß=105.2o, Z=4
The internal arrangement of these atoms is described as:
READ ALSO  MICHALSKIITE Mineral Details
Sorosilicates: of SiO4 tetrahedras combined mainly in pairs, also in larger combos which form isolated grp; Si2O7 grp with add’l anions, cations in octahedral [6] &/or other coordination; edge-sharing deformed CaO6 octahedra form 2-periodic single chains & double chains // [001]; corner-sharing of octahedra in double chains, & linked by Si2O7 grp creates ribbons // (100) linked by single chains & CO3 grp.1 Consisting of columns of Ca octahedra along c axis, which are linked into walls; in corrugated strip along b axis; these walls are linked by Si2O7 grp oriented along c axis; corrugated strips are held by separate Ca octahedra & CO3 grp; Ca octahedra & Si tetrahedra are very distorted.2 Distortions of columns of Ca—O octahedra are mostly explainable by shortening of shared edges; in Si2O7 grp Si—O bridge bonds are 1.656(7) & 1.678(7) Å & peripheral bonds are 1.602(7) & 1.616(7) Å & peripheral bonds are 1.602(7) & 1.617(7) Å & bridging Si—O—Si angle is 157o; inner O—O edges (avg 2.58 Å) are shorter than outer edges (2.71 Å), consistent with Coulombic forces in Si2O7 grp & with л-bonding mechanism.3 Consist of (CO3) grp in 1 layer, whereas (CaO8) polyhedra intertwine [Si2O7] pairs of tetrahedra in outer layer.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
READ ALSO  FERROSILITE Mineral Details

Physical Appearance (Habit)

When you find TILLEYITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As subhedral crystals, rounded grains, irregular plates
  • Twinning: On {100}, simple; rarely, lamellar
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If TILLEYITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In contact metamorphic zone between igneous rocks and limestones, formed at low pressure and high temperatureKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. TILLEYITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of TILLEYITE?The standard chemical formula for TILLEYITE is Ca5[Si2O7](CO3)2. This defines its elemental composition.
READ ALSO  TVEITITE-(Y) Mineral Details
2. Which crystal system does TILLEYITE belong to?TILLEYITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is TILLEYITE typically found in nature?The “habit” or typical appearance of TILLEYITE is described as As subhedral crystals, rounded grains, irregular plates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does TILLEYITE form?TILLEYITE is typically found in environments described as: In contact metamorphic zone between igneous rocks and limestones, formed at low pressure and high temperature. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to TILLEYITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of TILLEYITE, we recommend checking high-authority databases:

Final Thoughts

TILLEYITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca5[Si2O7](CO3)2 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
Scroll to Top