TINCALCONITE Mineral Details

Complete mineralogical data for TINCALCONITE. Chemical Formula: Na6[B4O5(OH)4]3(H2O)6·2H2O. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

TINCALCONITE

Na6[B4O5(OH)4]3(H2O)6·2H2O

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal trapezohedral

Space Group

R32

Point Group

3 2

Structure & Data

Crystal Structure

Borate structures are based on constitution of FBB with triangles (Tr) & tetrahedra (Tt); tetraborates; neso-tetraborates; 4(2Tr+2Tt): insular tetraborate; 4 edge-sharing Na(OH,H2O)6 octahedra form planar trig grp // (0001); 2 face-sharing Na(H2O)6 octahedra & borate grp, both oriented along [0001]; connect 4-membered grp of octahedra into 3-D framework.1 Structure consists of Na cations & borate anion held together by variety of elctrostactic interactions; these mostly involve lone pairs of H2O molecules, O atoms in OH grp, Na cations, & some H—bonding interactions.2 Nature of stabilization around each Na cation is unique; Na1 atom, loc at intersection of 1 [3] & 3 [3]-axes, is entirely surrounded by lone pairs from O4 atom of borate anion, resulting in distorted octahedral geometry (assessed on basis of closeness to 90o, is surrounded by lone pairs from 2 O4 atoms, 2 O5 atoms (also from borate anion), & 2 H2O molecules; Na2 atom therefore forms bridge btw borate anions; internal angles around Na2 are descriptive of more prf octahedral geometry; Na3 atom, loc on [3]-axis, is entirely surrounded by lone pairs from what appears to be 5 H2O molecules & it is here that we believe that previous structural work (Giacovazzo et al 1973) is in error; 3 of sites for H2O molecules are fully occupied (labeled as O11_5. H111_5 & H112_5 & other 2 are generated by symmetry; O11-Na2-O11′ angles are very large at 106.56(7)o & corresponding O11-Na3-O12 & O12-Na3-O12 angles are 75.5(2)o & 66.9(4)o resp; O12 atom is on gen position but was resulting in [6]- pattern displayed; in this diagram only 2 of atoms labeled as O12 are involved in each Na3 to Na3′ interation in unit cell; thus, each Na3 atom is pseudo penta-coordinated & only bridged by 2O atoms (from 2 solvated H2O molecules); this shows that tincalconite is best formulated as Na6[B4O5(OH)4]3.8H2O; add’l conclusions are drawn.3

Cell Data

a=11.140Å, c=21.207Å, Z=3

Geology & Identification

Geologic Occurrence

Dehydration of other sodium boratesTINCALCONITETINCALCONITE

Habit

Pseudo-octahedral crystals; commonly as powder or pseudomorphs

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare borax

If you are fascinated by the hidden structures of our planet, you have likely come across TINCALCONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about TINCALCONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, TINCALCONITE is defined by the chemical formula Na6[B4O5(OH)4]3(H2O)6·2H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. TINCALCONITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal trapezohedral.
  • Point Group: 3 2
  • Space Group: R32
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For TINCALCONITE, the dimensions of this microscopic building block are:
a=11.140Å, c=21.207Å, Z=3
The internal arrangement of these atoms is described as:
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Borate structures are based on constitution of FBB with triangles (Tr) & tetrahedra (Tt); tetraborates; neso-tetraborates; 4(2Tr+2Tt): insular tetraborate; 4 edge-sharing Na(OH,H2O)6 octahedra form planar trig grp // (0001); 2 face-sharing Na(H2O)6 octahedra & borate grp, both oriented along [0001]; connect 4-membered grp of octahedra into 3-D framework.1 Structure consists of Na cations & borate anion held together by variety of elctrostactic interactions; these mostly involve lone pairs of H2O molecules, O atoms in OH grp, Na cations, & some H—bonding interactions.2 Nature of stabilization around each Na cation is unique; Na1 atom, loc at intersection of 1 [3] & 3 [3]-axes, is entirely surrounded by lone pairs from O4 atom of borate anion, resulting in distorted octahedral geometry (assessed on basis of closeness to 90o, is surrounded by lone pairs from 2 O4 atoms, 2 O5 atoms (also from borate anion), & 2 H2O molecules; Na2 atom therefore forms bridge btw borate anions; internal angles around Na2 are descriptive of more prf octahedral geometry; Na3 atom, loc on [3]-axis, is entirely surrounded by lone pairs from what appears to be 5 H2O molecules & it is here that we believe that previous structural work (Giacovazzo et al 1973) is in error; 3 of sites for H2O molecules are fully occupied (labeled as O11_5. H111_5 & H112_5 & other 2 are generated by symmetry; O11-Na2-O11′ angles are very large at 106.56(7)o & corresponding O11-Na3-O12 & O12-Na3-O12 angles are 75.5(2)o & 66.9(4)o resp; O12 atom is on gen position but was resulting in [6]- pattern displayed; in this diagram only 2 of atoms labeled as O12 are involved in each Na3 to Na3′ interation in unit cell; thus, each Na3 atom is pseudo penta-coordinated & only bridged by 2O atoms (from 2 solvated H2O molecules); this shows that tincalconite is best formulated as Na6[B4O5(OH)4]3.8H2O; add’l conclusions are drawn.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find TINCALCONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Pseudo-octahedral crystals; commonly as powder or pseudomorphs
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If TINCALCONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Dehydration of other sodium boratesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. TINCALCONITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare boraxUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of TINCALCONITE?The standard chemical formula for TINCALCONITE is Na6[B4O5(OH)4]3(H2O)6·2H2O. This defines its elemental composition.2. Which crystal system does TINCALCONITE belong to?TINCALCONITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal trapezohedral class.3. How is TINCALCONITE typically found in nature?The “habit” or typical appearance of TINCALCONITE is described as Pseudo-octahedral crystals; commonly as powder or pseudomorphs. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does TINCALCONITE form?TINCALCONITE is typically found in environments described as: Dehydration of other sodium borates. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to TINCALCONITE?Yes, it is often associated with or related to other minerals such as: Compare borax.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of TINCALCONITE, we recommend checking high-authority databases:

Final Thoughts

TINCALCONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na6[B4O5(OH)4]3(H2O)6·2H2O and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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