TOLBACHITE Mineral Details

Complete mineralogical data for TOLBACHITE. Chemical Formula: CuCl2. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

TOLBACHITE

CuCl2

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/m

Point Group

2/m

Structure & Data

Crystal Structure

Halides: ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; simple halides w/o H2O, M:X = 1:2; edge-sharing CuCl4 □ planes form chains // [010]; these chains are linked into sheets // (001) by sharing corners of □ planes, giving CuCl4Cl2 in octahedral coordination.1 Contains Cu2+ Cl6 octahedra distorted such that there are 4 Cu—Cl equatorial bond distances [2.001(6) Å] & 2 much longer Cu—Cl apical bond [2.991(6) Å], (4+2) distortion; this octahedral environment is result of Jahn-Teller effect; each CuCl6 octahedron shares 2 Cl—Clequatorial edges with adjacent octahedra, & its apical Cl- ions are equatorial ligands for adjacent octahedra; this linkage results in corrugated octahedral sheets of composition CuCl2 || to (001); each sheet is electrostatically neutral, & linkage btw adjacent sheets is by Van der Waals forces, explaining why tolbachite quickly hydrates in air.2

Cell Data

a=6.90Å, b=3.30Å, c=6.82Å, ß=122.3o, Z=2

Geology & Identification

Geologic Occurrence

As fumarolic incrustations on basalt; in oxidized copper depostsTOLBACHITETOLBACHITE

Habit

Crystals, elongated, in fibrous, mosslike growths incrusting basalt

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across TOLBACHITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about TOLBACHITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, TOLBACHITE is defined by the chemical formula CuCl2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. TOLBACHITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For TOLBACHITE, the dimensions of this microscopic building block are:
a=6.90Å, b=3.30Å, c=6.82Å, ß=122.3o, Z=2
The internal arrangement of these atoms is described as:Halides: ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; simple halides w/o H2O, M:X = 1:2; edge-sharing CuCl4 □ planes form chains // [010]; these chains are linked into sheets // (001) by sharing corners of □ planes, giving CuCl4Cl2 in octahedral coordination.1 Contains Cu2+ Cl6 octahedra distorted such that there are 4 Cu—Cl equatorial bond distances [2.001(6) Å] & 2 much longer Cu—Cl apical bond [2.991(6) Å], (4+2) distortion; this octahedral environment is result of Jahn-Teller effect; each CuCl6 octahedron shares 2 Cl—Clequatorial edges with adjacent octahedra, & its apical Cl- ions are equatorial ligands for adjacent octahedra; this linkage results in corrugated octahedral sheets of composition CuCl2 || to (001); each sheet is electrostatically neutral, & linkage btw adjacent sheets is by Van der Waals forces, explaining why tolbachite quickly hydrates in air.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find TOLBACHITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals, elongated, in fibrous, mosslike growths incrusting basalt
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If TOLBACHITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: As fumarolic incrustations on basalt; in oxidized copper depostsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. TOLBACHITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of TOLBACHITE?The standard chemical formula for TOLBACHITE is CuCl2. This defines its elemental composition.2. Which crystal system does TOLBACHITE belong to?TOLBACHITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.
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3. How is TOLBACHITE typically found in nature?The “habit” or typical appearance of TOLBACHITE is described as Crystals, elongated, in fibrous, mosslike growths incrusting basalt. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does TOLBACHITE form?TOLBACHITE is typically found in environments described as: As fumarolic incrustations on basalt; in oxidized copper deposts. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to TOLBACHITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of TOLBACHITE, we recommend checking high-authority databases:

Final Thoughts

TOLBACHITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of CuCl2 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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