TROLLEITE Mineral Details

Complete mineralogical data for TROLLEITE. Chemical Formula: Al4(PO4)3(OH)3. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

TROLLEITE

Al4(PO4)3(OH)3

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

I2/c

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; 2 face-sharing Al[6], octahedra form Al2O6(OH)3 dimers that are corner-linked to form double chains // [001] which are further linked into 3-D framework by PO4 tetrahedra.1 Al has 2 diff coordinations in its structure; 1 is coordinated to 4 OH & 2 O & other to 3 OH & 2 O; 4 Al polyhedra, 2 of each type, are linked together by sharing OH—OH edges; these grp are connected by P tetrahedra.2 Structure consists of Al—O octahedral face-sharing dimers which link by corner-sharing OH grp to form infinite double-chain which runs || to [001] direction; [PO4] tetrahedra bridge these chains to produce very dense 3-D structure; structure is topologically related to that of lazulite, MgAl2 (OH)2[PO4]2; this is particularly evident if orientations of [PO4] tetrahedra are noted: lazulite tetrahedra & O packing can be superimposed ± upon those of trolleite.3

Cell Data

a=18.894Å, b=7.161Å, c=7.162Å, ß=99.99o, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermally altered phosphate zone of complex granite pegmatite; meteoriteTROLLEITETROLLEITE

Habit

Small acicular crystals, in radial aggregates; massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across TROLLEITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about TROLLEITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, TROLLEITE is defined by the chemical formula Al4(PO4)3(OH)3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. TROLLEITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: I2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For TROLLEITE, the dimensions of this microscopic building block are:
a=18.894Å, b=7.161Å, c=7.162Å, ß=99.99o, Z=4
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; 2 face-sharing Al[6], octahedra form Al2O6(OH)3 dimers that are corner-linked to form double chains // [001] which are further linked into 3-D framework by PO4 tetrahedra.1 Al has 2 diff coordinations in its structure; 1 is coordinated to 4 OH & 2 O & other to 3 OH & 2 O; 4 Al polyhedra, 2 of each type, are linked together by sharing OH—OH edges; these grp are connected by P tetrahedra.2 Structure consists of Al—O octahedral face-sharing dimers which link by corner-sharing OH grp to form infinite double-chain which runs || to [001] direction; [PO4] tetrahedra bridge these chains to produce very dense 3-D structure; structure is topologically related to that of lazulite, MgAl2 (OH)2[PO4]2; this is particularly evident if orientations of [PO4] tetrahedra are noted: lazulite tetrahedra & O packing can be superimposed ± upon those of trolleite.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find TROLLEITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Small acicular crystals, in radial aggregates; massive
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If TROLLEITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermally altered phosphate zone of complex granite pegmatite; meteoriteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. TROLLEITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of TROLLEITE?The standard chemical formula for TROLLEITE is Al4(PO4)3(OH)3. This defines its elemental composition.
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2. Which crystal system does TROLLEITE belong to?TROLLEITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is TROLLEITE typically found in nature?The “habit” or typical appearance of TROLLEITE is described as Small acicular crystals, in radial aggregates; massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does TROLLEITE form?TROLLEITE is typically found in environments described as: In hydrothermally altered phosphate zone of complex granite pegmatite; meteorite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to TROLLEITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of TROLLEITE, we recommend checking high-authority databases:

Final Thoughts

TROLLEITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Al4(PO4)3(OH)3 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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