URANOCIRCITE Mineral Details

Complete mineralogical data for URANOCIRCITE. Chemical Formula: Ba(UO2)2(PO4)2(H2O)4·6H2O. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

URANOCIRCITE

Ba(UO2)2(PO4)2(H2O)4·6H2O

Crystal System

Tetragonal

Crystal Class

Ditetragonal dipyramidal

Space Group

P4/nnc

Point Group

4/m 2/m 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units; uranyl phosphate & arsenates, UO2:RO4 = 1:1; UO2+4 tetragonal di-∆ share corners with 4 RO4 tetrahedra, forming continuous sheets in which UO2 surrounded by 4 RO4 in turn surrounded by 4 UO2; sheets alternate with sheets of divalent cations & H2O molecules.2 PO4 radicals & (UO3)O4 polyhedra are linked into tetragonal corrugated layers of composition [UO2(PO4)]n-n || to (001); these layers are held together mainly via OH—H bonds to H2O molecules forming □ btw layers at 2 levels; centers of ½ of □ are taken by M in metatorbernite types, these being linked to 4 H2O & to 2 O atoms in uranyl grp; torbernite type has add’l H2O (n of 2-4), which increases c parameter; centers of H2O □ remain empty in natroautinite type, while 1 of H2O molecules is repl by Ba, Na, K or NH4 & H2O, which have low electro-negativity & are mostly univalent.3

Cell Data

a=7.01Å, c=20.46Å, Z=2

Geology & Identification

Geologic Occurrence

In granite-syenite pegmatites; hydrothermal high-temperature sulfide veins; sandstone U-V deposits; detritalURANOCIRCITEURANOCIRCITE

Habit

Botryoidal to reniform, colloform banded, columnar, dense massive; dendritic; rare macro crystals, modified cubes

Twinning

On {111}, rare

Relationships

RELATIONSHIP TO OTHER MINERALS

Autunite group; in series with thorianite; fluorite type structure

If you are fascinated by the hidden structures of our planet, you have likely come across URANOCIRCITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about URANOCIRCITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, URANOCIRCITE is defined by the chemical formula Ba(UO2)2(PO4)2(H2O)4·6H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. URANOCIRCITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Ditetragonal dipyramidal.
  • Point Group: 4/m 2/m 2/m
  • Space Group: P4/nnc
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For URANOCIRCITE, the dimensions of this microscopic building block are:
a=7.01Å, c=20.46Å, Z=2
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units; uranyl phosphate & arsenates, UO2:RO4 = 1:1; UO2+4 tetragonal di-∆ share corners with 4 RO4 tetrahedra, forming continuous sheets in which UO2 surrounded by 4 RO4 in turn surrounded by 4 UO2; sheets alternate with sheets of divalent cations & H2O molecules.2 PO4 radicals & (UO3)O4 polyhedra are linked into tetragonal corrugated layers of composition [UO2(PO4)]n-n || to (001); these layers are held together mainly via OH—H bonds to H2O molecules forming □ btw layers at 2 levels; centers of ½ of □ are taken by M in metatorbernite types, these being linked to 4 H2O & to 2 O atoms in uranyl grp; torbernite type has add’l H2O (n of 2-4), which increases c parameter; centers of H2O □ remain empty in natroautinite type, while 1 of H2O molecules is repl by Ba, Na, K or NH4 & H2O, which have low electro-negativity & are mostly univalent.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find URANOCIRCITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Botryoidal to reniform, colloform banded, columnar, dense massive; dendritic; rare macro crystals, modified cubes
  • Twinning: On {111}, rare
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If URANOCIRCITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In granite-syenite pegmatites; hydrothermal high-temperature sulfide veins; sandstone U-V deposits; detritalKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. URANOCIRCITE is often related to other species, either through similar chemistry or structure.Relationship Data: Autunite group; in series with thorianite; fluorite type structureUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of URANOCIRCITE?The standard chemical formula for URANOCIRCITE is Ba(UO2)2(PO4)2(H2O)4·6H2O. This defines its elemental composition.2. Which crystal system does URANOCIRCITE belong to?URANOCIRCITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Ditetragonal dipyramidal class.
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3. How is URANOCIRCITE typically found in nature?The “habit” or typical appearance of URANOCIRCITE is described as Botryoidal to reniform, colloform banded, columnar, dense massive; dendritic; rare macro crystals, modified cubes. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does URANOCIRCITE form?URANOCIRCITE is typically found in environments described as: In granite-syenite pegmatites; hydrothermal high-temperature sulfide veins; sandstone U-V deposits; detrital. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to URANOCIRCITE?Yes, it is often associated with or related to other minerals such as: Autunite group; in series with thorianite; fluorite type structure.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of URANOCIRCITE, we recommend checking high-authority databases:

Final Thoughts

URANOCIRCITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ba(UO2)2(PO4)2(H2O)4·6H2O and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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