VANADINITE Mineral Details

Complete mineralogical data for VANADINITE. Chemical Formula: Pb5(VO4)3Cl. Crystal System: Hexagonal. Learn about its geologic occurrence, habit, and identification.

VANADINITE

Pb5(VO4)3Cl

Crystal System

Hexagonal

Crystal Class

Hexagonal dipyramidal

Space Group

P63/m

Point Group

6/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with large cations, (OH, etc.):RO4 = 0.33:1; M[9] polyhedra share faces to form chains // [0001] linked into hexagonal array by sharing edges & corners with RO4 tetrahedra; F & OH ions loc in wide hexagonal channels // [0001].2 Apatite type, 2 types of Pb diff in coordination: Pb1 with 9 O, PbII with 6 O + Cl; identical with chlorapatite type; Cl atoms lie within regular octahedra.3 Cl ion is surrounded by 6 divalent Pb ions at corners of reg octahedron; coordination of O around V is tetrahedral.4

Cell Data

a=10.31Å, c=7.34Å, Z=2

Geology & Identification

Geologic Occurrence

Most common rock-forming phosphate; in igneous rocks, syenites, alkaline rocks, carbonatites, pegmatitesVANADINITEVANADINITE

Habit

Prismatic hexagonal macro crystals, elongated or tabular; many forms; granular, globular-reniform, nodular, massive

Twinning

As contact twins on {1121} or {1013}

Relationships

RELATIONSHIP TO OTHER MINERALS

Apatite supergroup; forms series with mimetite, endlichite = mid-member

If you are fascinated by the hidden structures of our planet, you have likely come across VANADINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about VANADINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, VANADINITE is defined by the chemical formula Pb5(VO4)3Cl.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. VANADINITE crystallizes in the Hexagonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Hexagonal dipyramidal.
  • Point Group: 6/m
  • Space Group: P63/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For VANADINITE, the dimensions of this microscopic building block are:
a=10.31Å, c=7.34Å, Z=2
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with large cations, (OH, etc.):RO4 = 0.33:1; M[9] polyhedra share faces to form chains // [0001] linked into hexagonal array by sharing edges & corners with RO4 tetrahedra; F & OH ions loc in wide hexagonal channels // [0001].2 Apatite type, 2 types of Pb diff in coordination: Pb1 with 9 O, PbII with 6 O + Cl; identical with chlorapatite type; Cl atoms lie within regular octahedra.3 Cl ion is surrounded by 6 divalent Pb ions at corners of reg octahedron; coordination of O around V is tetrahedral.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find VANADINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic hexagonal macro crystals, elongated or tabular; many forms; granular, globular-reniform, nodular, massive
  • Twinning: As contact twins on {1121} or {1013}
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If VANADINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Most common rock-forming phosphate; in igneous rocks, syenites, alkaline rocks, carbonatites, pegmatitesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. VANADINITE is often related to other species, either through similar chemistry or structure.Relationship Data: Apatite supergroup; forms series with mimetite, endlichite = mid-memberUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of VANADINITE?The standard chemical formula for VANADINITE is Pb5(VO4)3Cl. This defines its elemental composition.2. Which crystal system does VANADINITE belong to?VANADINITE crystallizes in the Hexagonal system. Its internal symmetry is further classified under the Hexagonal dipyramidal class.
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3. How is VANADINITE typically found in nature?The “habit” or typical appearance of VANADINITE is described as Prismatic hexagonal macro crystals, elongated or tabular; many forms; granular, globular-reniform, nodular, massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does VANADINITE form?VANADINITE is typically found in environments described as: Most common rock-forming phosphate; in igneous rocks, syenites, alkaline rocks, carbonatites, pegmatites. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to VANADINITE?Yes, it is often associated with or related to other minerals such as: Apatite supergroup; forms series with mimetite, endlichite = mid-member.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of VANADINITE, we recommend checking high-authority databases:

Final Thoughts

VANADINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb5(VO4)3Cl and a structure defined by the Hexagonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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