VAUXITE Mineral Details

Complete mineralogical data for VAUXITE. Chemical Formula: Fe2+Al2(PO4)2(OH)2(H2O)2·4H2O. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

VAUXITE

Fe2+Al2(PO4)2(OH)2(H2O)2·4H2O

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with medium-sized cations, (OH, etc.):RO4 = 1:1 < 2:1; chains // [001] of alternating, edge-sharing Fe[6] & Al[6] octahedra corner-linked on 2 sides to chains of corner-sharing PO4 tetrahedra & Al[6] octahedra, forming triple chain connected by corner-sharing Al & Fe octahedra to form framework with H2O molecules in cavities.1 Chains || to c axis consisting of (Fe,Mn,Mg) octahedra linked via common OH vertices & further linked via O vertices to PO4 tetrahedra; these chains are linked along a axis by same PO4 tetrahedra into layers of composition {(Fe3+, Al)2(H2O)2(PO4)2(OH)2}2- || to (010), layers being connected by (Fe,Mn,Mg) octahedra, which are connected via 2 opposite O vertices to 4 outer O vertices of P tetrahedra; these are weakest bonds in structure; other 4 vertices of (Fe,Mn,Mg) octahedron remain free & bear H2O molecules; further 2 H2O molecules in formula are of zeolite type & lie in holes in structure; a parameter ½ that in metavauxite; twinning occurs on a axis.2 Based on bldg unit oriented || to c axis & composed of chain of Fe2 & Al2 edge-sharing octahedra & 2 chains of corner-sharing P2 tetrahedra & Al1 octahedra, interconnected via corners & P1 tetrahedra; neighboring bldg units are interconnected by Al3 octahedra & via Fe1 octahedra; framework is completed with 2 non-coordinated H2O molecules; latter, together with 2 OH grp & other 4 coordinated H2O molecules, form complex H—bonding network whose interations further compact whole framework; both FTIR & Raman spectra show in H2O stretching region, broad absorption consisting of several overlapping components due to 6 H2O molecules plus OH grp.3

Cell Data

a=9.13Å, b=11.59Å, c=6.14Å, α=98.3o, ß=92.0o, γ=108.4o, Z=2

Geology & Identification

Geologic Occurrence

Secondary mineral derived from alteration of apatiteVAUXITEVAUXITE

Habit

Tabular, elongated crystals; radial to subparallel aggregates, nodular

Twinning

On {010}, twin and composition plane

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across VAUXITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about VAUXITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, VAUXITE is defined by the chemical formula Fe2+Al2(PO4)2(OH)2(H2O)2·4H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. VAUXITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For VAUXITE, the dimensions of this microscopic building block are:
a=9.13Å, b=11.59Å, c=6.14Å, α=98.3o, ß=92.0o, γ=108.4o, Z=2
The internal arrangement of these atoms is described as:
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Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with medium-sized cations, (OH, etc.):RO4 = 1:1 < 2:1; chains // [001] of alternating, edge-sharing Fe[6] & Al[6] octahedra corner-linked on 2 sides to chains of corner-sharing PO4 tetrahedra & Al[6] octahedra, forming triple chain connected by corner-sharing Al & Fe octahedra to form framework with H2O molecules in cavities.1 Chains || to c axis consisting of (Fe,Mn,Mg) octahedra linked via common OH vertices & further linked via O vertices to PO4 tetrahedra; these chains are linked along a axis by same PO4 tetrahedra into layers of composition {(Fe3+, Al)2(H2O)2(PO4)2(OH)2}2- || to (010), layers being connected by (Fe,Mn,Mg) octahedra, which are connected via 2 opposite O vertices to 4 outer O vertices of P tetrahedra; these are weakest bonds in structure; other 4 vertices of (Fe,Mn,Mg) octahedron remain free & bear H2O molecules; further 2 H2O molecules in formula are of zeolite type & lie in holes in structure; a parameter ½ that in metavauxite; twinning occurs on a axis.2 Based on bldg unit oriented || to c axis & composed of chain of Fe2 & Al2 edge-sharing octahedra & 2 chains of corner-sharing P2 tetrahedra & Al1 octahedra, interconnected via corners & P1 tetrahedra; neighboring bldg units are interconnected by Al3 octahedra & via Fe1 octahedra; framework is completed with 2 non-coordinated H2O molecules; latter, together with 2 OH grp & other 4 coordinated H2O molecules, form complex H—bonding network whose interations further compact whole framework; both FTIR & Raman spectra show in H2O stretching region, broad absorption consisting of several overlapping components due to 6 H2O molecules plus OH grp.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find VAUXITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Tabular, elongated crystals; radial to subparallel aggregates, nodular
  • Twinning: On {010}, twin and composition plane
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If VAUXITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral derived from alteration of apatiteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. VAUXITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of VAUXITE?The standard chemical formula for VAUXITE is Fe2+Al2(PO4)2(OH)2(H2O)2·4H2O. This defines its elemental composition.2. Which crystal system does VAUXITE belong to?VAUXITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.3. How is VAUXITE typically found in nature?The “habit” or typical appearance of VAUXITE is described as Tabular, elongated crystals; radial to subparallel aggregates, nodular. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does VAUXITE form?VAUXITE is typically found in environments described as: Secondary mineral derived from alteration of apatite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to VAUXITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of VAUXITE, we recommend checking high-authority databases:

Final Thoughts

VAUXITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Fe2+Al2(PO4)2(OH)2(H2O)2·4H2O and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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