VIVIANITE Mineral Details

Complete mineralogical data for VIVIANITE. Chemical Formula: Fe2+3(PO4)2(H2O)6·2H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

VIVIANITE

Fe2+3(PO4)2(H2O)6·2H2O

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/m

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with medium-sized cations, RO4:H2O ≤ 1:2.5; dimers of M[6] octahedra & insular M[6] octahedra, corner-linked to RO4 tetrahedra to form sheets // (010); linked by H—bonds.2 2 types of Fe octahedron: FeO2(H2O)4 & FeO4(H2O)2, latter being paired via O—O edges; single & paired octahedra are linked via PO4 tetrhedra into ≠ layers || to (010).3

Cell Data

a=10.09Å, b=13.45Å, c=4.70Å, ß=104.3o, Z=2

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of metallic ore deposits and complex granite pegmatites; replacing organic material in fossils; bogsVIVIANITEVIVIANITE

Habit

Prismatic macro crystals, flattened, elongated; stellate groups, incrustations, concretionary, powdery

Twinning

Translation gliding T(010), t[001]

Relationships

RELATIONSHIP TO OTHER MINERALS

Vivianite group

If you are fascinated by the hidden structures of our planet, you have likely come across VIVIANITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about VIVIANITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, VIVIANITE is defined by the chemical formula Fe2+3(PO4)2(H2O)6·2H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. VIVIANITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For VIVIANITE, the dimensions of this microscopic building block are:
a=10.09Å, b=13.45Å, c=4.70Å, ß=104.3o, Z=2
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with medium-sized cations, RO4:H2O ≤ 1:2.5; dimers of M[6] octahedra & insular M[6] octahedra, corner-linked to RO4 tetrahedra to form sheets // (010); linked by H—bonds.2 2 types of Fe octahedron: FeO2(H2O)4 & FeO4(H2O)2, latter being paired via O—O edges; single & paired octahedra are linked via PO4 tetrhedra into ≠ layers || to (010).3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find VIVIANITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic macro crystals, flattened, elongated; stellate groups, incrustations, concretionary, powdery
  • Twinning: Translation gliding T(010), t[001]
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If VIVIANITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of metallic ore deposits and complex granite pegmatites; replacing organic material in fossils; bogsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. VIVIANITE is often related to other species, either through similar chemistry or structure.Relationship Data: Vivianite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of VIVIANITE?The standard chemical formula for VIVIANITE is Fe2+3(PO4)2(H2O)6·2H2O. This defines its elemental composition.2. Which crystal system does VIVIANITE belong to?VIVIANITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.
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3. How is VIVIANITE typically found in nature?The “habit” or typical appearance of VIVIANITE is described as Prismatic macro crystals, flattened, elongated; stellate groups, incrustations, concretionary, powdery. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does VIVIANITE form?VIVIANITE is typically found in environments described as: Secondary mineral in oxidized zone of metallic ore deposits and complex granite pegmatites; replacing organic material in fossils; bogs. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to VIVIANITE?Yes, it is often associated with or related to other minerals such as: Vivianite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of VIVIANITE, we recommend checking high-authority databases:

Final Thoughts

VIVIANITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Fe2+3(PO4)2(H2O)6·2H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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