VLASOVITE Mineral Details

Complete mineralogical data for VLASOVITE. Chemical Formula: Na2Zr[Si4O11]. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

VLASOVITE

Na2Zr[Si4O11]

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/c

Point Group

2/m

Structure & Data

Crystal Structure

Inosilicates: tetrahedra form chains of infinite length with 6-periodic single chains; 2 SiO4 tetrahedra connected to Si6O18 6 = periodic single chains // [101] to form 4-membered rings connected into framework by Zr octahedra with Na in cavities.1 Framework of Si tetrahedra & Zr octahedra, holes containing Na atoms (CN of 6 & 7); SiO4 tetrahedra form □ rings linked into staggered chains, which until recently led to allotment of mineral to chain subclass.2 Structure is new type of silicate with infinite chains-ribbons of [Si6O22]∞.3 There are 2 tetrahedrally coordinated Si sites with distance of 1.62 Å, & symmetry-related Na(2B) sites are separated by 1.525 Å, & 1 octahedrally coordinated Zr site with = 2.085 Å; there are 2 Na sites: Na(1) site is [7]-coordinated with = 2.620 Å; Na(2) site is split into 2 subsites, Na(2A) & Na(2B) with separation of 0.829 Å, & symmetry-related Na(2B) sites are separated by 1.525 Å; Na(2A) is octahedrally coordinated, & Na(2B) is [5]-coordinated, & their occupancies are 0.826(8) & 0.092(4) Na, resp; thus Na(1) & aggregate Na(2) sites are each fully occupied; in xl structure, 4-membered rings of (SiO4) tetrahedra link together to form [Si4O11]6- chain; these chains of tetrahedra & Zr octahedra link together to form heteropolyhedral framework with channels extending along [001]; 3 channels contain Na atoms, which are bonded to O atoms of octahedron-tetrahedron framework; H2O content is variable to none.4

Cell Data

a=10.98Å, b=10.00Å, c=8.52Å, ß=100.4o, Z=4

Geology & Identification

Geologic Occurrence

In nepheline syenite, syenite pegmatites, contact differentiated alkalic massif; in miarolitic cavities in ejected blocks of peralkalic graniteVLASOVITEVLASOVITE

Habit

In macro crystals; more commonly as subrounded to irregularly shaped grains and aggregates of such grains

Twinning

Twin plane [010}, uncommon

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare narsarsukite

If you are fascinated by the hidden structures of our planet, you have likely come across VLASOVITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about VLASOVITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, VLASOVITE is defined by the chemical formula Na2Zr[Si4O11].This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. VLASOVITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For VLASOVITE, the dimensions of this microscopic building block are:
a=10.98Å, b=10.00Å, c=8.52Å, ß=100.4o, Z=4
The internal arrangement of these atoms is described as:
READ ALSO  GLAUCOCERINITE Mineral Details
Inosilicates: tetrahedra form chains of infinite length with 6-periodic single chains; 2 SiO4 tetrahedra connected to Si6O18 6 = periodic single chains // [101] to form 4-membered rings connected into framework by Zr octahedra with Na in cavities.1 Framework of Si tetrahedra & Zr octahedra, holes containing Na atoms (CN of 6 & 7); SiO4 tetrahedra form □ rings linked into staggered chains, which until recently led to allotment of mineral to chain subclass.2 Structure is new type of silicate with infinite chains-ribbons of [Si6O22]∞.3 There are 2 tetrahedrally coordinated Si sites with distance of 1.62 Å, & symmetry-related Na(2B) sites are separated by 1.525 Å, & 1 octahedrally coordinated Zr site with = 2.085 Å; there are 2 Na sites: Na(1) site is [7]-coordinated with = 2.620 Å; Na(2) site is split into 2 subsites, Na(2A) & Na(2B) with separation of 0.829 Å, & symmetry-related Na(2B) sites are separated by 1.525 Å; Na(2A) is octahedrally coordinated, & Na(2B) is [5]-coordinated, & their occupancies are 0.826(8) & 0.092(4) Na, resp; thus Na(1) & aggregate Na(2) sites are each fully occupied; in xl structure, 4-membered rings of (SiO4) tetrahedra link together to form [Si4O11]6- chain; these chains of tetrahedra & Zr octahedra link together to form heteropolyhedral framework with channels extending along [001]; 3 channels contain Na atoms, which are bonded to O atoms of octahedron-tetrahedron framework; H2O content is variable to none.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find VLASOVITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: In macro crystals; more commonly as subrounded to irregularly shaped grains and aggregates of such grains
  • Twinning: Twin plane [010}, uncommon
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If VLASOVITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In nepheline syenite, syenite pegmatites, contact differentiated alkalic massif; in miarolitic cavities in ejected blocks of peralkalic graniteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. VLASOVITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare narsarsukiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of VLASOVITE?The standard chemical formula for VLASOVITE is Na2Zr[Si4O11]. This defines its elemental composition.2. Which crystal system does VLASOVITE belong to?VLASOVITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is VLASOVITE typically found in nature?The “habit” or typical appearance of VLASOVITE is described as In macro crystals; more commonly as subrounded to irregularly shaped grains and aggregates of such grains. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does VLASOVITE form?VLASOVITE is typically found in environments described as: In nepheline syenite, syenite pegmatites, contact differentiated alkalic massif; in miarolitic cavities in ejected blocks of peralkalic granite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to VLASOVITE?Yes, it is often associated with or related to other minerals such as: Compare narsarsukite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of VLASOVITE, we recommend checking high-authority databases:

Final Thoughts

VLASOVITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na2Zr[Si4O11] and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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