WALLISITE Mineral Details

Complete mineralogical data for WALLISITE. Chemical Formula: PbTlCuAs2S5. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

WALLISITE

PbTlCuAs2S5

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; XS3 ∆, poly-sulfarsenites; edge-sharing pairs of (Cu,Ag)4 tetrhedra & corner-sharing pairs of AsS3 ∆ are joined by As & S atoms to form double chains linked by (Pb,Tl)[8] & (Tl,Pb)[2] atoms.1 Consists of Cu2As4S10 double chains || b”, which are joined by Pb, Tl atoms; each constituent single chain corresponds to CuAs2S7; each double chain is composed by Cu2S6 double tetrahedra & As2S5 ∆ grp; Pb,Tl(1) position has [8] coordination of S & consists mainly of Pb atoms, Tl, Pb(2) position has many 2 nearest S neighbors & consitsts mainly of Tl atoms; complete (001) cleavage is well explained by structure; isomorphous with hatchite.2

Cell Data

a=9.215Å, b=8.524Å, c=7.980Å, α=55.983o, ß=62.500o, γ=69.400o, Z=2

Geology & Identification

Geologic Occurrence

Overgrowing other lead sulfosaltsWALLISITEWALLISITE

Habit

As small crystals, usually massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Forms series with hatchite

If you are fascinated by the hidden structures of our planet, you have likely come across WALLISITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about WALLISITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, WALLISITE is defined by the chemical formula PbTlCuAs2S5.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. WALLISITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For WALLISITE, the dimensions of this microscopic building block are:
a=9.215Å, b=8.524Å, c=7.980Å, α=55.983o, ß=62.500o, γ=69.400o, Z=2
The internal arrangement of these atoms is described as:Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; XS3 ∆, poly-sulfarsenites; edge-sharing pairs of (Cu,Ag)4 tetrhedra & corner-sharing pairs of AsS3 ∆ are joined by As & S atoms to form double chains linked by (Pb,Tl)[8] & (Tl,Pb)[2] atoms.1 Consists of Cu2As4S10 double chains || b”, which are joined by Pb, Tl atoms; each constituent single chain corresponds to CuAs2S7; each double chain is composed by Cu2S6 double tetrahedra & As2S5 ∆ grp; Pb,Tl(1) position has [8] coordination of S & consists mainly of Pb atoms, Tl, Pb(2) position has many 2 nearest S neighbors & consitsts mainly of Tl atoms; complete (001) cleavage is well explained by structure; isomorphous with hatchite.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find WALLISITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As small crystals, usually massive
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If WALLISITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Overgrowing other lead sulfosaltsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. WALLISITE is often related to other species, either through similar chemistry or structure.Relationship Data: Forms series with hatchiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of WALLISITE?The standard chemical formula for WALLISITE is PbTlCuAs2S5. This defines its elemental composition.2. Which crystal system does WALLISITE belong to?WALLISITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.
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3. How is WALLISITE typically found in nature?The “habit” or typical appearance of WALLISITE is described as As small crystals, usually massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does WALLISITE form?WALLISITE is typically found in environments described as: Overgrowing other lead sulfosalts. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to WALLISITE?Yes, it is often associated with or related to other minerals such as: Forms series with hatchite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of WALLISITE, we recommend checking high-authority databases:

Final Thoughts

WALLISITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbTlCuAs2S5 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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