WARDITE Mineral Details

Complete mineralogical data for WARDITE. Chemical Formula: NaAl3(PO4)2(OH)4(H2O)2. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

WARDITE

NaAl3(PO4)2(OH)4(H2O)2

Crystal System

Tetragonal

Crystal Class

Tetragonal trapezohedral

Space Group

P41212

Point Group

4 2 2

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with large & medium-sized cations, (OH, etc.):RO4 = 2:1; corner-sharing M[6] octahedra form sheet of interconnected 8-membered rings // (001) linked by PO4 tetrahedra & Na atoms.2 Layers of Al & Na coordination polyhedra sharing vertices & edges; these sheets,|| to a axes, are connected to each other in c direction by PO4 tetrahedra & H— bonds; features acct for prf {001} cleavage.3 Consists of sheets made of edge-sharing Na-polyhedra & Al-octahedra along with vertex-sharing Al-octahedra, || to (001), connected by P-tetrahedra & H—bonds to form (001) layer-type structure, which well explains pronounced {001} cleavage of wardite xl; 4 xllographically independent H sites occur in structure of wardite, 2 belonging to H2O molecule & 2 forming OH grp; loc of H atoms allows definition of extensive network of H—bonds: H atoms belong to H2O molecule form strong H—bonds, whereas both H atoms belonging to independent OH grp form weak interactions with bifurcated bonding schemes.4

Cell Data

a=7.0577Å, c=19.0559Å, Z=4

Geology & Identification

Geologic Occurrence

Component of low-temperature phosphatic nodules; uncommon species in complex zoned pegmatitesWARDITEWARDITE

Habit

Dipyramidal pseudo-octahedral macro crystals, striated

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Wardite group; Al – analog of cyrilovite

If you are fascinated by the hidden structures of our planet, you have likely come across WARDITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about WARDITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, WARDITE is defined by the chemical formula NaAl3(PO4)2(OH)4(H2O)2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. WARDITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Tetragonal trapezohedral.
  • Point Group: 4 2 2
  • Space Group: P41212
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For WARDITE, the dimensions of this microscopic building block are:
a=7.0577Å, c=19.0559Å, Z=4
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with large & medium-sized cations, (OH, etc.):RO4 = 2:1; corner-sharing M[6] octahedra form sheet of interconnected 8-membered rings // (001) linked by PO4 tetrahedra & Na atoms.2 Layers of Al & Na coordination polyhedra sharing vertices & edges; these sheets,|| to a axes, are connected to each other in c direction by PO4 tetrahedra & H— bonds; features acct for prf {001} cleavage.3 Consists of sheets made of edge-sharing Na-polyhedra & Al-octahedra along with vertex-sharing Al-octahedra, || to (001), connected by P-tetrahedra & H—bonds to form (001) layer-type structure, which well explains pronounced {001} cleavage of wardite xl; 4 xllographically independent H sites occur in structure of wardite, 2 belonging to H2O molecule & 2 forming OH grp; loc of H atoms allows definition of extensive network of H—bonds: H atoms belong to H2O molecule form strong H—bonds, whereas both H atoms belonging to independent OH grp form weak interactions with bifurcated bonding schemes.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find WARDITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Dipyramidal pseudo-octahedral macro crystals, striated
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If WARDITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Component of low-temperature phosphatic nodules; uncommon species in complex zoned pegmatitesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. WARDITE is often related to other species, either through similar chemistry or structure.Relationship Data: Wardite group; Al – analog of cyriloviteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of WARDITE?The standard chemical formula for WARDITE is NaAl3(PO4)2(OH)4(H2O)2. This defines its elemental composition.
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2. Which crystal system does WARDITE belong to?WARDITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Tetragonal trapezohedral class.3. How is WARDITE typically found in nature?The “habit” or typical appearance of WARDITE is described as Dipyramidal pseudo-octahedral macro crystals, striated. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does WARDITE form?WARDITE is typically found in environments described as: Component of low-temperature phosphatic nodules; uncommon species in complex zoned pegmatites. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to WARDITE?Yes, it is often associated with or related to other minerals such as: Wardite group; Al – analog of cyrilovite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of WARDITE, we recommend checking high-authority databases:

Final Thoughts

WARDITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of NaAl3(PO4)2(OH)4(H2O)2 and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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