ZEKTZERITE Mineral Details

Complete mineralogical data for ZEKTZERITE. Chemical Formula: □NaLiZr[Si6O15]. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

ZEKTZERITE

□NaLiZr[Si6O15]

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Cmca

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Inosilicates: tetrahedra form chains of infinite length; with 6-periodic double chains; 3 kinds of chains all // [001]: undulating Si6O18 6-periodic double chains with 4-membered rings; chains of edge-sharing distorted (Na,K)O6 octahedra; chains of alternating edge-sharing LiO4 tetrahedra & ZrO6 octahedra.2 Xl structure is 3-D framework consisting of (a) edge-sharing Na-polyhedral chains, (b) octahedral-tetrahedral chains, formed by alternating Li tetrahedra & Zr octahedra sharing edges, & (c) corrugated double-silicate chains with 6-tetrahedron with avg Li-O distance of 1.959 Å, shows strong angular distortion; Zr octahedron is nearly regular with avg Zr-O distance of 2.074 Å; Na atom occurs in irregular cavity formed by corrugation of silicate double chains; it is coordinated to 6 O atoms at distances of 2.37-2.67 Å, & 4 more O atoms at distances of 3.12- 3.23 Å; avg Si—O bond lengths within Si(1), Si(2) & Si(3) tetrahedra are 1.614, 1.616 & 1.610 Å; Si—O —Si bond angles involving O lying on mirro planes avg 155.7o, whereas those within single silicate chain avg 147.6o; larger Si—O—Si angles are assoc with shorter Si—O bonds; zektzerite is isostructural with tuhualite.3 Structure consists of 6-tetrahedral-repeat corrugated double silicate chains connected into 3-D framework by edge-sharing Li tetrahedral-Zr octahedral chains; at room temp Na+ ions occur at Na(1) site loc within cylindrical channels created by corrugation of silicate double chains; 2nd Na site, Na(2), occurs above & below Zr octahedron & is nominally vacant at room temp; above 773 K, vacancies are created at Na(1) site due to migration of Na+ ions from Na(1) to Na(2) site.4

Cell Data

a=14.33Å, b=17.35Å, c=10.16Å, Z=8

Geology & Identification

Geologic Occurrence

A primary igneous mineral and in vesicles of some silicic lavas, as comendites and pantelleritesZEKTZERITEZEKTZERITE

Habit

In well-formed tabular crystals, flattened, with pyramidal terminations; irregular mosslike aggregates

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Tuhualite group; ormerly listed with milarite group

If you are fascinated by the hidden structures of our planet, you have likely come across ZEKTZERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about ZEKTZERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, ZEKTZERITE is defined by the chemical formula □NaLiZr[Si6O15].This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. ZEKTZERITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Cmca
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For ZEKTZERITE, the dimensions of this microscopic building block are:
a=14.33Å, b=17.35Å, c=10.16Å, Z=8
The internal arrangement of these atoms is described as:
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Inosilicates: tetrahedra form chains of infinite length; with 6-periodic double chains; 3 kinds of chains all // [001]: undulating Si6O18 6-periodic double chains with 4-membered rings; chains of edge-sharing distorted (Na,K)O6 octahedra; chains of alternating edge-sharing LiO4 tetrahedra & ZrO6 octahedra.2 Xl structure is 3-D framework consisting of (a) edge-sharing Na-polyhedral chains, (b) octahedral-tetrahedral chains, formed by alternating Li tetrahedra & Zr octahedra sharing edges, & (c) corrugated double-silicate chains with 6-tetrahedron with avg Li-O distance of 1.959 Å, shows strong angular distortion; Zr octahedron is nearly regular with avg Zr-O distance of 2.074 Å; Na atom occurs in irregular cavity formed by corrugation of silicate double chains; it is coordinated to 6 O atoms at distances of 2.37-2.67 Å, & 4 more O atoms at distances of 3.12- 3.23 Å; avg Si—O bond lengths within Si(1), Si(2) & Si(3) tetrahedra are 1.614, 1.616 & 1.610 Å; Si—O —Si bond angles involving O lying on mirro planes avg 155.7o, whereas those within single silicate chain avg 147.6o; larger Si—O—Si angles are assoc with shorter Si—O bonds; zektzerite is isostructural with tuhualite.3 Structure consists of 6-tetrahedral-repeat corrugated double silicate chains connected into 3-D framework by edge-sharing Li tetrahedral-Zr octahedral chains; at room temp Na+ ions occur at Na(1) site loc within cylindrical channels created by corrugation of silicate double chains; 2nd Na site, Na(2), occurs above & below Zr octahedron & is nominally vacant at room temp; above 773 K, vacancies are created at Na(1) site due to migration of Na+ ions from Na(1) to Na(2) site.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find ZEKTZERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: In well-formed tabular crystals, flattened, with pyramidal terminations; irregular mosslike aggregates
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If ZEKTZERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: A primary igneous mineral and in vesicles of some silicic lavas, as comendites and pantelleritesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. ZEKTZERITE is often related to other species, either through similar chemistry or structure.Relationship Data: Tuhualite group; ormerly listed with milarite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of ZEKTZERITE?The standard chemical formula for ZEKTZERITE is □NaLiZr[Si6O15]. This defines its elemental composition.
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2. Which crystal system does ZEKTZERITE belong to?ZEKTZERITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is ZEKTZERITE typically found in nature?The “habit” or typical appearance of ZEKTZERITE is described as In well-formed tabular crystals, flattened, with pyramidal terminations; irregular mosslike aggregates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does ZEKTZERITE form?ZEKTZERITE is typically found in environments described as: A primary igneous mineral and in vesicles of some silicic lavas, as comendites and pantellerites. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to ZEKTZERITE?Yes, it is often associated with or related to other minerals such as: Tuhualite group; ormerly listed with milarite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of ZEKTZERITE, we recommend checking high-authority databases:

Final Thoughts

ZEKTZERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of □NaLiZr[Si6O15] and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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