ZIRKELITE Mineral Details

Complete mineralogical data for ZIRKELITE. Chemical Formula: (Ca,Th,Ce)Zr(Zr,Ti)2O7. Crystal System: Isometric. Learn about its geologic occurrence, habit, and identification.

ZIRKELITE

(Ca,Th,Ce)Zr(Zr,Ti)2O7

Crystal System

Isometric

Crystal Class

Cubic hexoctahedral

Space Group

Fm3m

Point Group

4/m 3 2/m

Structure & Data

Crystal Structure

Cation coordinations varying from [2] to [10] & polyhedra linked in var ways with large cations; sheets of edge-sharing octahedra; corner-sharing TiO6 octahedra form sheets of 3- & 6- membered rings // (0001), similar to [110] sheets in pyrochlore; attached add’l TiO5 trig di-∆; these sheets alternate with sheets consisting of corner-sharing CaO8 cubes & ZrO7 polyhedra.1 Closely related to fluorite structure; Ca (M1) is coordinated by 8 O atoms lying at corners of distorted cube; Th & U substitute for Ca on this site; Zr (M2) is surrounded by 7 O atoms at corners of truncated cube & contains about 15% substituted Ti; of remaining 3 cation sites, M3 & M5 are surrounded by 6 O forming distorted octahedra while M4 occurring in trig bi-∆ [5] coordination; Ti, Fe, Nb & Zr occupy M3 site, Fe & Ti M4 site & Ti & Nb M5 site; 2 types of octahedra (M3 & M5) join together at their vertices to form 3 & 6 membered rings, similar to planes of octahedra || to {111} in pyrochlore structure; M4 metal site is situated within 6 membered ring & occupies split position displaced towards X4 O atoms on 1 side of cavity; these 2 equivalent M4 sites are separated by distance of 0.53(2) Å; metal atoms occur in planes || to (001) & alternately contain M3, M4, & M5 or M1 & M2 cation sites; they are derived from metal only (111) planes of fluorite structure.2

Cell Data

a=5.06Å, Z=2

Geology & Identification

Geologic Occurrence

In a magnetite-pyroxenite carbonatite; late-stage differntiate in layered intrusionZIRKELITEZIRKELITE

Habit

Crystals are flattened octahedra

Twinning

Common on {111}, as fourlings, polysynthetic

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with calciobetafite; compare tazheranite

If you are fascinated by the hidden structures of our planet, you have likely come across ZIRKELITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about ZIRKELITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, ZIRKELITE is defined by the chemical formula (Ca,Th,Ce)Zr(Zr,Ti)2O7.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. ZIRKELITE crystallizes in the Isometric system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Cubic hexoctahedral.
  • Point Group: 4/m 3 2/m
  • Space Group: Fm3m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For ZIRKELITE, the dimensions of this microscopic building block are:
a=5.06Å, Z=2
The internal arrangement of these atoms is described as:
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Cation coordinations varying from [2] to [10] & polyhedra linked in var ways with large cations; sheets of edge-sharing octahedra; corner-sharing TiO6 octahedra form sheets of 3- & 6- membered rings // (0001), similar to [110] sheets in pyrochlore; attached add’l TiO5 trig di-∆; these sheets alternate with sheets consisting of corner-sharing CaO8 cubes & ZrO7 polyhedra.1 Closely related to fluorite structure; Ca (M1) is coordinated by 8 O atoms lying at corners of distorted cube; Th & U substitute for Ca on this site; Zr (M2) is surrounded by 7 O atoms at corners of truncated cube & contains about 15% substituted Ti; of remaining 3 cation sites, M3 & M5 are surrounded by 6 O forming distorted octahedra while M4 occurring in trig bi-∆ [5] coordination; Ti, Fe, Nb & Zr occupy M3 site, Fe & Ti M4 site & Ti & Nb M5 site; 2 types of octahedra (M3 & M5) join together at their vertices to form 3 & 6 membered rings, similar to planes of octahedra || to {111} in pyrochlore structure; M4 metal site is situated within 6 membered ring & occupies split position displaced towards X4 O atoms on 1 side of cavity; these 2 equivalent M4 sites are separated by distance of 0.53(2) Å; metal atoms occur in planes || to (001) & alternately contain M3, M4, & M5 or M1 & M2 cation sites; they are derived from metal only (111) planes of fluorite structure.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find ZIRKELITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals are flattened octahedra
  • Twinning: Common on {111}, as fourlings, polysynthetic
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If ZIRKELITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In a magnetite-pyroxenite carbonatite; late-stage differntiate in layered intrusionKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. ZIRKELITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with calciobetafite; compare tazheraniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of ZIRKELITE?The standard chemical formula for ZIRKELITE is (Ca,Th,Ce)Zr(Zr,Ti)2O7. This defines its elemental composition.
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2. Which crystal system does ZIRKELITE belong to?ZIRKELITE crystallizes in the Isometric system. Its internal symmetry is further classified under the Cubic hexoctahedral class.3. How is ZIRKELITE typically found in nature?The “habit” or typical appearance of ZIRKELITE is described as Crystals are flattened octahedra. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does ZIRKELITE form?ZIRKELITE is typically found in environments described as: In a magnetite-pyroxenite carbonatite; late-stage differntiate in layered intrusion. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to ZIRKELITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with calciobetafite; compare tazheranite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of ZIRKELITE, we recommend checking high-authority databases:

Final Thoughts

ZIRKELITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of (Ca,Th,Ce)Zr(Zr,Ti)2O7 and a structure defined by the Isometric system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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