LEUCITE Mineral Details

Complete mineralogical data for LEUCITE. Chemical Formula: K[Si2AlO6]. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

LEUCITE

K[Si2AlO6]

Crystal System

Tetragonal

Crystal Class

Tetragonal dipyramidal

Space Group

I41/a

Point Group

4/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework w/o add’l anions with 4-membered rings of SiO4 & AlO4 tetrahedra (Al:Si = 1:2) connected into framework containing 6-, 8-, 12-membered rings; large cations lodged in cavities; converts to cubic over 605o C.2 Framework of Al & Si tetrahedra, holes filled by large atoms; if smaller atoms repl these, i.e. Cs by Na, holes also lodge H2O in proportional amts.3 Wyart (1940) showed that framework of leucite is same as that of analcime & that s.g. is I41/a, which was confirmed by Náry-Szabó (1942); Wyart (1940) also described transition of high temp, isometric leucite to low temp tetragonal polymorph; unquenchable inversion causes tetragonal leucite to be intensely twinned, which has has long been known; to refine structure of leucite, Peacor (1968) heated his xl until cells parameters were all = & collected X-ray data at 635oC; Mazzi et al (1976) were able to find xl fragment with sufficient little twinning, to refine tetragonal polymorph; at high temp leucite framework is fully extended; with decreasing temp tetrahedra rotate to partially collapsed cages, allowing shorter K—O bond lengths.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; leucite is cubic polymorph with structure of analcime room temp.6 See “Additional Structures” tab for entry(s).5,7,8a,8b,8c

Cell Data

a=13.05Å, c=13.75Å, Z=16

Geology & Identification

Geologic Occurrence

With K-rich mafic-ultramafic lavas, bypabssal rocksLEUCITELEUCITE

Habit

Commonly euhedral, cubic macro crystals; as disseminated grains, rarley granular, massive

Twinning

Common-repeated on {110}, {101}

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family; K – analog of ammonioleucite

If you are fascinated by the hidden structures of our planet, you have likely come across LEUCITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about LEUCITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, LEUCITE is defined by the chemical formula K[Si2AlO6].This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. LEUCITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Tetragonal dipyramidal.
  • Point Group: 4/m
  • Space Group: I41/a
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For LEUCITE, the dimensions of this microscopic building block are:
a=13.05Å, c=13.75Å, Z=16
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework w/o add’l anions with 4-membered rings of SiO4 & AlO4 tetrahedra (Al:Si = 1:2) connected into framework containing 6-, 8-, 12-membered rings; large cations lodged in cavities; converts to cubic over 605o C.2 Framework of Al & Si tetrahedra, holes filled by large atoms; if smaller atoms repl these, i.e. Cs by Na, holes also lodge H2O in proportional amts.3 Wyart (1940) showed that framework of leucite is same as that of analcime & that s.g. is I41/a, which was confirmed by Náry-Szabó (1942); Wyart (1940) also described transition of high temp, isometric leucite to low temp tetragonal polymorph; unquenchable inversion causes tetragonal leucite to be intensely twinned, which has has long been known; to refine structure of leucite, Peacor (1968) heated his xl until cells parameters were all = & collected X-ray data at 635oC; Mazzi et al (1976) were able to find xl fragment with sufficient little twinning, to refine tetragonal polymorph; at high temp leucite framework is fully extended; with decreasing temp tetrahedra rotate to partially collapsed cages, allowing shorter K—O bond lengths.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; leucite is cubic polymorph with structure of analcime room temp.6 See “Additional Structures” tab for entry(s).5,7,8a,8b,8cThis internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find LEUCITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Commonly euhedral, cubic macro crystals; as disseminated grains, rarley granular, massive
  • Twinning: Common-repeated on {110}, {101}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If LEUCITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: With K-rich mafic-ultramafic lavas, bypabssal rocksKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. LEUCITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family; K – analog of ammonioleuciteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of LEUCITE?The standard chemical formula for LEUCITE is K[Si2AlO6]. This defines its elemental composition.
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2. Which crystal system does LEUCITE belong to?LEUCITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Tetragonal dipyramidal class.3. How is LEUCITE typically found in nature?The “habit” or typical appearance of LEUCITE is described as Commonly euhedral, cubic macro crystals; as disseminated grains, rarley granular, massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does LEUCITE form?LEUCITE is typically found in environments described as: With K-rich mafic-ultramafic lavas, bypabssal rocks. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to LEUCITE?Yes, it is often associated with or related to other minerals such as: Zeolite family; K – analog of ammonioleucite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of LEUCITE, we recommend checking high-authority databases:

Final Thoughts

LEUCITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of K[Si2AlO6] and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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