ERIONITE-Na Mineral Details

Complete mineralogical data for ERIONITE-Na. Chemical Formula: Na10[Si26Al10O72]·30H2O. Crystal System: Hexagonal. Learn about its geologic occurrence, habit, and identification.

Table of Contents

ERIONITE-Na

Na10[Si26Al10O72]·30H2O

Crystal System

Hexagonal

Crystal Class

Dihexagonal dipyramidal

Space Group

P63/mmc

Point Group

6/m 2/m 2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with columns // [0001] of double 6-membered rings alternating with cancrinite-type cages; large ‘erionite’-type cages btw columns bounded by 23 planes with larger openings formed by 8-membered rings; K is lodged in cancrinite-type cages, & Ca in erionite-type cages.2 Typical fibrous zeolite with chains (readily distinguished in structure) are based on wollastonite type & are joined in to zonotlite type strips with 8-sided rings; xonotlite type strips link up to give hexagonal Al—Si—O rings, which are resposible for symmetry of mineral.3 Eironite is 1 of 6-ring zeolites, grp that also incl offretite & levyne among others (Gottardi & Galli (1985)); framework (type ERI) is constructed of 6-rings in sequence AABAAC…., 1st proposed by Staples & Gard (1959), & confirmed by later refinements, e.g. Alberti et al (1997); this staking array produces columns of cancrinite cages alternating with double 6-ring (D6R) cages (formed by A 6-rings) & of erionite cavities btw B or C 6-rings.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; erionites structure is related to offretite with which it may form intergrowths with stacking faults, & levyne on which it forms epitactic growths; 3 minerals have 4-, 6-, & 8- membered rings; they diff in stacking of single & double 6-membered rings, resulting in diff c dimensions & diff sized & shaped cages; Si,Al disordered; Ca is most abundant extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7,8a,8b,9

Cell Data

a=13.21Å, c=15.05Å, Z=1

Geology & Identification

Geologic Occurrence

In vugs of volcanic massive rocksERIONITE-NaERIONITE-Na

Habit

Prismatic crystals, in radiating groups; fibrous, wool-like (original)

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family, erionite subgroup

If you are fascinated by the hidden structures of our planet, you have likely come across ERIONITE-Na. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about ERIONITE-Na. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, ERIONITE-Na is defined by the chemical formula Na10[Si26Al10O72]·30H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. ERIONITE-Na crystallizes in the Hexagonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dihexagonal dipyramidal.
  • Point Group: 6/m 2/m 2/m
  • Space Group: P63/mmc
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For ERIONITE-Na, the dimensions of this microscopic building block are:
a=13.21Å, c=15.05Å, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with columns // [0001] of double 6-membered rings alternating with cancrinite-type cages; large ‘erionite’-type cages btw columns bounded by 23 planes with larger openings formed by 8-membered rings; K is lodged in cancrinite-type cages, & Ca in erionite-type cages.2 Typical fibrous zeolite with chains (readily distinguished in structure) are based on wollastonite type & are joined in to zonotlite type strips with 8-sided rings; xonotlite type strips link up to give hexagonal Al—Si—O rings, which are resposible for symmetry of mineral.3 Eironite is 1 of 6-ring zeolites, grp that also incl offretite & levyne among others (Gottardi & Galli (1985)); framework (type ERI) is constructed of 6-rings in sequence AABAAC…., 1st proposed by Staples & Gard (1959), & confirmed by later refinements, e.g. Alberti et al (1997); this staking array produces columns of cancrinite cages alternating with double 6-ring (D6R) cages (formed by A 6-rings) & of erionite cavities btw B or C 6-rings.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; erionites structure is related to offretite with which it may form intergrowths with stacking faults, & levyne on which it forms epitactic growths; 3 minerals have 4-, 6-, & 8- membered rings; they diff in stacking of single & double 6-membered rings, resulting in diff c dimensions & diff sized & shaped cages; Si,Al disordered; Ca is most abundant extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7,8a,8b,9This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find ERIONITE-Na in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic crystals, in radiating groups; fibrous, wool-like (original)
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If ERIONITE-Na exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In vugs of volcanic massive rocksKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. ERIONITE-Na is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family, erionite subgroupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of ERIONITE-Na?The standard chemical formula for ERIONITE-Na is Na10[Si26Al10O72]·30H2O. This defines its elemental composition.
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2. Which crystal system does ERIONITE-Na belong to?ERIONITE-Na crystallizes in the Hexagonal system. Its internal symmetry is further classified under the Dihexagonal dipyramidal class.3. How is ERIONITE-Na typically found in nature?The “habit” or typical appearance of ERIONITE-Na is described as Prismatic crystals, in radiating groups; fibrous, wool-like (original). This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does ERIONITE-Na form?ERIONITE-Na is typically found in environments described as: In vugs of volcanic massive rocks. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to ERIONITE-Na?Yes, it is often associated with or related to other minerals such as: Zeolite family, erionite subgroup.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of ERIONITE-Na, we recommend checking high-authority databases:

Final Thoughts

ERIONITE-Na is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na10[Si26Al10O72]·30H2O and a structure defined by the Hexagonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.

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