PÉLIGOTITE Mineral Details

Complete mineralogical data for PÉLIGOTITE. Chemical Formula: Na6(UO2)(SO4)4(H2O)4. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

Table of Contents

PÉLIGOTITE

Na6(UO2)(SO4)4(H2O)4

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Contain [(UO2)(SO4)4]6- clusters in which 1 SO4 grp has bidentate linkage with UO7 polyhedron; Na—O polyhedra link clusters into thick heteropolyhedral layers & link layers into frameworks.1 Structures of klaprothite (R1 = 2.22%) & péligotite (R1 = 2.28%) contain [(UO2)(SO4)4]6- clusters in which one SO4 grp has bidentate linkage with UO7 polyhedron; Na—O polyhedra link clusters into thick heteropolyhedral layers & link layers into frameworks; structures diff in configuration of Na—O polyhedra that link layers; structure of ottohahnite (R1 = 2.65%) contains [(UO2)4(SO4)10]12- clusters in which each UO7 polyhedron has bidentate linkage with 1 SO4 grp; Na—O polyhedra link clusters into thin heteropolyhedral slice & also link slices into framework.2

Cell Data

a=9.8151Å, b=9.9575Å, c=10.6289Å, α=88.680o, ß=73.990o, γ=89.205o, Z=2

Geology & Identification

Geologic Occurrence

Secondary weathering of sulfides in sandstonePÉLIGOTITEPÉLIGOTITE

Habit

Forms equant concave micro rhombs with rounded edges

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorph of klaprothite

If you are fascinated by the hidden structures of our planet, you have likely come across PÉLIGOTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PÉLIGOTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PÉLIGOTITE is defined by the chemical formula Na6(UO2)(SO4)4(H2O)4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PÉLIGOTITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PÉLIGOTITE, the dimensions of this microscopic building block are:
a=9.8151Å, b=9.9575Å, c=10.6289Å, α=88.680o, ß=73.990o, γ=89.205o, Z=2
The internal arrangement of these atoms is described as:Contain [(UO2)(SO4)4]6- clusters in which 1 SO4 grp has bidentate linkage with UO7 polyhedron; Na—O polyhedra link clusters into thick heteropolyhedral layers & link layers into frameworks.1 Structures of klaprothite (R1 = 2.22%) & péligotite (R1 = 2.28%) contain [(UO2)(SO4)4]6- clusters in which one SO4 grp has bidentate linkage with UO7 polyhedron; Na—O polyhedra link clusters into thick heteropolyhedral layers & link layers into frameworks; structures diff in configuration of Na—O polyhedra that link layers; structure of ottohahnite (R1 = 2.65%) contains [(UO2)4(SO4)10]12- clusters in which each UO7 polyhedron has bidentate linkage with 1 SO4 grp; Na—O polyhedra link clusters into thin heteropolyhedral slice & also link slices into framework.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find PÉLIGOTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Forms equant concave micro rhombs with rounded edges
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PÉLIGOTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary weathering of sulfides in sandstoneKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PÉLIGOTITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorph of klaprothiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of PÉLIGOTITE?The standard chemical formula for PÉLIGOTITE is Na6(UO2)(SO4)4(H2O)4. This defines its elemental composition.2. Which crystal system does PÉLIGOTITE belong to?PÉLIGOTITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.
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3. How is PÉLIGOTITE typically found in nature?The “habit” or typical appearance of PÉLIGOTITE is described as Forms equant concave micro rhombs with rounded edges. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PÉLIGOTITE form?PÉLIGOTITE is typically found in environments described as: Secondary weathering of sulfides in sandstone. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PÉLIGOTITE?Yes, it is often associated with or related to other minerals such as: Dimorph of klaprothite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PÉLIGOTITE, we recommend checking high-authority databases:

Final Thoughts

PÉLIGOTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na6(UO2)(SO4)4(H2O)4 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.

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