BEUDANTITE Mineral Details

Complete mineralogical data for BEUDANTITE. Chemical Formula: PbFe3+3(AsO4)(SO4)(OH)6. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

Table of Contents

BEUDANTITE

PbFe3+3(AsO4)(SO4)(OH)6

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal scalenohedral

Space Group

R3m

Point Group

3 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized & large cations,(OH, etc.):RO4 = 3:1; corner-sharing M(O,OH)6 octahedra in 3- & 6-membered rings linked into sheets // (0001); 3 O atoms of 3-membered ring form trig base of RO4 tetrahedra, which have their apices alternating up & down; sheets linked by large cations; alunite structure type.2 Alunite type; Pb(Ba) CN = 12, Al(Fe) has CN = 6.3 Pb2+ cation, which is expected to occupy 3a site (origin) in R3m, is disordered, its position being about 0.28 Å from origin along x; thus, together with its s.g. equivalent positions, electron density appears as regular hexagon with sides 0.28 Å in x-y plane; owing to electron-density overlap of these positions, fig appears to be toroid, centered on origin & surrounded by cage of 12 O atoms; this effect of displacement of Pb from its expected special position has been attributed to Pb(II) 6s2 lone-pair interaction with neighboring atom bond-pairs; bond lengths from Pb to O atoms vary btw 2.64 & 3.10 Å, these being longer (in max) & shorter (in min) than corresponding distances in plumbojarosite.4

Cell Data

a=7.31Å, c=17.03Å, Z=3

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of polymetallic depsositsBEUDANTITEBEUDANTITE

Habit

As tabular crystals, pseudocubes, pseudo-octahedra; also microcrystalline massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Beudantite group; related to alunite-jarosite group; isostructural with crandallite, alunite; (AsO4) – analog of corkite

If you are fascinated by the hidden structures of our planet, you have likely come across BEUDANTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BEUDANTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BEUDANTITE is defined by the chemical formula PbFe3+3(AsO4)(SO4)(OH)6.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BEUDANTITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal scalenohedral.
  • Point Group: 3 2/m
  • Space Group: R3m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BEUDANTITE, the dimensions of this microscopic building block are:
a=7.31Å, c=17.03Å, Z=3
The internal arrangement of these atoms is described as:
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Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized & large cations,(OH, etc.):RO4 = 3:1; corner-sharing M(O,OH)6 octahedra in 3- & 6-membered rings linked into sheets // (0001); 3 O atoms of 3-membered ring form trig base of RO4 tetrahedra, which have their apices alternating up & down; sheets linked by large cations; alunite structure type.2 Alunite type; Pb(Ba) CN = 12, Al(Fe) has CN = 6.3 Pb2+ cation, which is expected to occupy 3a site (origin) in R3m, is disordered, its position being about 0.28 Å from origin along x; thus, together with its s.g. equivalent positions, electron density appears as regular hexagon with sides 0.28 Å in x-y plane; owing to electron-density overlap of these positions, fig appears to be toroid, centered on origin & surrounded by cage of 12 O atoms; this effect of displacement of Pb from its expected special position has been attributed to Pb(II) 6s2 lone-pair interaction with neighboring atom bond-pairs; bond lengths from Pb to O atoms vary btw 2.64 & 3.10 Å, these being longer (in max) & shorter (in min) than corresponding distances in plumbojarosite.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find BEUDANTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As tabular crystals, pseudocubes, pseudo-octahedra; also microcrystalline massive
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BEUDANTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of polymetallic depsositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BEUDANTITE is often related to other species, either through similar chemistry or structure.Relationship Data: Beudantite group; related to alunite-jarosite group; isostructural with crandallite, alunite; (AsO4) – analog of corkiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BEUDANTITE?The standard chemical formula for BEUDANTITE is PbFe3+3(AsO4)(SO4)(OH)6. This defines its elemental composition.
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2. Which crystal system does BEUDANTITE belong to?BEUDANTITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal scalenohedral class.3. How is BEUDANTITE typically found in nature?The “habit” or typical appearance of BEUDANTITE is described as As tabular crystals, pseudocubes, pseudo-octahedra; also microcrystalline massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BEUDANTITE form?BEUDANTITE is typically found in environments described as: Secondary mineral in oxidized zone of polymetallic depsosits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BEUDANTITE?Yes, it is often associated with or related to other minerals such as: Beudantite group; related to alunite-jarosite group; isostructural with crandallite, alunite; (AsO4) – analog of corkite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BEUDANTITE, we recommend checking high-authority databases:

Final Thoughts

BEUDANTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbFe3+3(AsO4)(SO4)(OH)6 and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.

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