OLIVENITE Mineral Details

Complete mineralogical data for OLIVENITE. Chemical Formula: Cu2(AsO4)(OH). Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

Table of Contents

OLIVENITE

Cu2(AsO4)(OH)

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/n

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; chains // [001] of edge-sharing MO4 (OH)2 octahedra flanked by RO4 tetrahedra that cross-link adjacent chains to form open framework; channels in framework contain dimers of edge-sharing MO3O (OH) trig di-∆ that share corners with octahedra & tetrahedra of framework; andalusite structure type.2 Adamite is isostructural with andalusite, which is homo-structural with olivenite; Cu & Zn have CN of 5 & 6.3 Analog of andalusite; consists of chains of edge-sharing, distorted [CuO4(OH)3] octahedra extending || to [001]; chains cross-linked by isolated AsO4 tetrahedra by corner-sharing, forming channels in which dimers of edge-sharing, distorted [CuO4(OH)3] octahedra extending || to [001]; these chains cross-linked by isolated AsO4 tetrahedra by corner-sharing, forming channels in which dimers of edge-sharing [CuO4(OH)] trig bi-∆ are loc; structure is stabilized by medium to weak O—H…O H—bonds.4 Converts from Monoclinic, P21/n to Orthorhombic, Pnnm at ~ 200o C.5

Cell Data

a=8.589Å, b=8.207Å, c=5.928Å, ß=90.09o, Z=4

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of Cu-depositsOLIVENITEOLIVENITE

Habit

As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Olivenite group; forms series with adamite

If you are fascinated by the hidden structures of our planet, you have likely come across OLIVENITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about OLIVENITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, OLIVENITE is defined by the chemical formula Cu2(AsO4)(OH).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. OLIVENITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/n
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For OLIVENITE, the dimensions of this microscopic building block are:
a=8.589Å, b=8.207Å, c=5.928Å, ß=90.09o, Z=4
The internal arrangement of these atoms is described as:
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Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; chains // [001] of edge-sharing MO4 (OH)2 octahedra flanked by RO4 tetrahedra that cross-link adjacent chains to form open framework; channels in framework contain dimers of edge-sharing MO3O (OH) trig di-∆ that share corners with octahedra & tetrahedra of framework; andalusite structure type.2 Adamite is isostructural with andalusite, which is homo-structural with olivenite; Cu & Zn have CN of 5 & 6.3 Analog of andalusite; consists of chains of edge-sharing, distorted [CuO4(OH)3] octahedra extending || to [001]; chains cross-linked by isolated AsO4 tetrahedra by corner-sharing, forming channels in which dimers of edge-sharing, distorted [CuO4(OH)3] octahedra extending || to [001]; these chains cross-linked by isolated AsO4 tetrahedra by corner-sharing, forming channels in which dimers of edge-sharing [CuO4(OH)] trig bi-∆ are loc; structure is stabilized by medium to weak O—H…O H—bonds.4 Converts from Monoclinic, P21/n to Orthorhombic, Pnnm at ~ 200o C.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find OLIVENITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If OLIVENITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of Cu-depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. OLIVENITE is often related to other species, either through similar chemistry or structure.Relationship Data: Olivenite group; forms series with adamiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of OLIVENITE?The standard chemical formula for OLIVENITE is Cu2(AsO4)(OH). This defines its elemental composition.
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2. Which crystal system does OLIVENITE belong to?OLIVENITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is OLIVENITE typically found in nature?The “habit” or typical appearance of OLIVENITE is described as As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does OLIVENITE form?OLIVENITE is typically found in environments described as: Secondary mineral in oxidized zone of Cu-deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to OLIVENITE?Yes, it is often associated with or related to other minerals such as: Olivenite group; forms series with adamite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of OLIVENITE, we recommend checking high-authority databases:

Final Thoughts

OLIVENITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Cu2(AsO4)(OH) and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.

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