DIRENZOITE Mineral Details

Complete mineralogical data for DIRENZOITE. Chemical Formula: NaK6MgCa2[Si47Al13O120]·36H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

Table of Contents

DIRENZOITE

NaK6MgCa2[Si47Al13O120]·36H2O

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pmmn

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Framework of direnzoite & isotypic synthetic ECR-1 (Leonowicz & Vaughn, 1987, Chen et al 1996, Gualtieri et al 2006, & Gualtieri 2008) consists of layers of mordenite & mazzite connected in regular 1:1 stacking sequence; 6 non-framework sites & 14 distinct sites for H2O molecules were determined in direnzoite (Galli & Gualtieri 2008); 3 sites are occupied by K ions with Na, Ca, & Mg distributed over 3 other distinct sites; all non-framework sites display partial occupancy; K1 was refined at origin, inside 8-ring channels of mazzite sheet with [8]-coordination with 6 framework O & 2 H2O molecules; K2 is loc within large 12-ring channel of mordenite sheet at window formed by 8-membered ring with [9]-coordination with 6 framework O atoms & 3 H2O molecules; K3 is found within 12-ring channel close to bottom 6-membered ring; it has [8]-coordination invironment with 4 O atoms & 2 H2O molecules; Ca also in 12-ring channel has distorted ∆-like, [5]-coordination with H2O molecules; Na is in 8-ring channels of mordenite sheet with [4]-coordination environment with 1 framework O & 3 H2O; like in mazzite, Mg is at center of gmelinite cage, totally surrounded by H2O molecules.2 6 extra-framework sites & 14 H2O molecules identifed within zeolite micropores; 3 extra framework sites occupied by K+ ions; others occupied by Na+, Ca++ & Mg++; sites C3 & C3b correspond resp in K3 & Ca in direnzoite; K1, K2 & Na correspond to H2O molecules sites.3

Cell Data

a=7.579Å, b=18.201Å, c=26.154Å, Z=lacking

Geology & Identification

Geologic Occurrence

In cavities in xenolitic rockDIRENZOITEDIRENZOITE

Habit

fibrous micro crystals

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across DIRENZOITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about DIRENZOITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, DIRENZOITE is defined by the chemical formula NaK6MgCa2[Si47Al13O120]·36H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. DIRENZOITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pmmn
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For DIRENZOITE, the dimensions of this microscopic building block are:
a=7.579Å, b=18.201Å, c=26.154Å, Z=lacking
The internal arrangement of these atoms is described as:Framework of direnzoite & isotypic synthetic ECR-1 (Leonowicz & Vaughn, 1987, Chen et al 1996, Gualtieri et al 2006, & Gualtieri 2008) consists of layers of mordenite & mazzite connected in regular 1:1 stacking sequence; 6 non-framework sites & 14 distinct sites for H2O molecules were determined in direnzoite (Galli & Gualtieri 2008); 3 sites are occupied by K ions with Na, Ca, & Mg distributed over 3 other distinct sites; all non-framework sites display partial occupancy; K1 was refined at origin, inside 8-ring channels of mazzite sheet with [8]-coordination with 6 framework O & 2 H2O molecules; K2 is loc within large 12-ring channel of mordenite sheet at window formed by 8-membered ring with [9]-coordination with 6 framework O atoms & 3 H2O molecules; K3 is found within 12-ring channel close to bottom 6-membered ring; it has [8]-coordination invironment with 4 O atoms & 2 H2O molecules; Ca also in 12-ring channel has distorted ∆-like, [5]-coordination with H2O molecules; Na is in 8-ring channels of mordenite sheet with [4]-coordination environment with 1 framework O & 3 H2O; like in mazzite, Mg is at center of gmelinite cage, totally surrounded by H2O molecules.2 6 extra-framework sites & 14 H2O molecules identifed within zeolite micropores; 3 extra framework sites occupied by K+ ions; others occupied by Na+, Ca++ & Mg++; sites C3 & C3b correspond resp in K3 & Ca in direnzoite; K1, K2 & Na correspond to H2O molecules sites.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find DIRENZOITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: fibrous micro crystals
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If DIRENZOITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In cavities in xenolitic rockKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. DIRENZOITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of DIRENZOITE?The standard chemical formula for DIRENZOITE is NaK6MgCa2[Si47Al13O120]·36H2O. This defines its elemental composition.
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2. Which crystal system does DIRENZOITE belong to?DIRENZOITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is DIRENZOITE typically found in nature?The “habit” or typical appearance of DIRENZOITE is described as fibrous micro crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does DIRENZOITE form?DIRENZOITE is typically found in environments described as: In cavities in xenolitic rock. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to DIRENZOITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of DIRENZOITE, we recommend checking high-authority databases:

Final Thoughts

DIRENZOITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of NaK6MgCa2[Si47Al13O120]·36H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.

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